Ontology type: schema:Chapter
1993
AUTHORS ABSTRACTThese lectures review the results of a number of susceptibility studies of supercooled liquids and glasses. Dielectric response and specific-heat spectroscopy can investigate the motions that occur at the glass transition, Tg, as the liquid slows down and approaches an amorphous solid. In contrast to predictions of mode-coupling theory, these experiments give no evidence of a critical slowing down occurring at high temperature but rather indicate a divergence of the relaxation-time scales at a much lower value close to the Kauzmann temperature where the extrapolation of the entropy of the liquid state crosses that of the crystal. In addition, the dielectric relaxation of the liquid (for all temperatures and samples measured) can be scaled onto a single master curve. In addition to this primary relaxation, dielectric susceptibility can give detailed information about the secondary (Johari-Goldstein) relaxation occurring in the glass phase below Tg. For several glasses, the dielectric studies indicate that the secondary relaxation is due to the activation of single, uncoupled, entities over barriers which have a Gaussian distribution of energies. More... »
PAGES259-283
Phase Transitions and Relaxation in Systems with Competing Energy Scales
ISBN
978-94-010-4843-9
978-94-011-1908-5
http://scigraph.springernature.com/pub.10.1007/978-94-011-1908-5_12
DOIhttp://dx.doi.org/10.1007/978-94-011-1908-5_12
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1010458859
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "The James Franck Institute and The Department of Physics, The University of Chicago, 5640 South Ellis Avenue, 60637, Chicago, Illinois, USA",
"id": "http://www.grid.ac/institutes/grid.170205.1",
"name": [
"The James Franck Institute and The Department of Physics, The University of Chicago, 5640 South Ellis Avenue, 60637, Chicago, Illinois, USA"
],
"type": "Organization"
},
"familyName": "Nagel",
"givenName": "Sidney R.",
"id": "sg:person.0727503755.14",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727503755.14"
],
"type": "Person"
}
],
"datePublished": "1993",
"datePublishedReg": "1993-01-01",
"description": "These lectures review the results of a number of susceptibility studies of supercooled liquids and glasses. Dielectric response and specific-heat spectroscopy can investigate the motions that occur at the glass transition, Tg, as the liquid slows down and approaches an amorphous solid. In contrast to predictions of mode-coupling theory, these experiments give no evidence of a critical slowing down occurring at high temperature but rather indicate a divergence of the relaxation-time scales at a much lower value close to the Kauzmann temperature where the extrapolation of the entropy of the liquid state crosses that of the crystal. In addition, the dielectric relaxation of the liquid (for all temperatures and samples measured) can be scaled onto a single master curve. In addition to this primary relaxation, dielectric susceptibility can give detailed information about the secondary (Johari-Goldstein) relaxation occurring in the glass phase below Tg. For several glasses, the dielectric studies indicate that the secondary relaxation is due to the activation of single, uncoupled, entities over barriers which have a Gaussian distribution of energies.",
"editor": [
{
"familyName": "Riste",
"givenName": "Tormod",
"type": "Person"
},
{
"familyName": "Sherrington",
"givenName": "David",
"type": "Person"
}
],
"genre": "chapter",
"id": "sg:pub.10.1007/978-94-011-1908-5_12",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": {
"isbn": [
"978-94-010-4843-9",
"978-94-011-1908-5"
],
"name": "Phase Transitions and Relaxation in Systems with Competing Energy Scales",
"type": "Book"
},
"keywords": [
"secondary relaxation",
"susceptibility studies",
"mode-coupling theory",
"relaxation time scale",
"state crosses",
"specific heat spectroscopy",
"dielectric susceptibility",
"Supercooled Liquids",
"Kauzmann temperature",
"dielectric response",
"critical slowing",
"dielectric studies",
"glass phase",
"dielectric relaxation",
"glass",
"glass transition",
"amorphous solids",
"liquid",
"primary relaxation",
"relaxation",
"Tg",
"single master curve",
"spectroscopy",
"high temperature",
"crystals",
"energy",
"temperature",
"Gaussian distribution",
"transition",
"detailed information",
"master curve",
"solids",
"motion",
"entropy",
"lower values",
"theory",
"extrapolation",
"addition",
"phase",
"experiments",
"slowing",
"distribution",
"prediction",
"barriers",
"curves",
"scale",
"study",
"divergence",
"susceptibility",
"values",
"contrast",
"results",
"cross",
"lectures",
"information",
"number",
"activation",
"entities",
"evidence",
"response"
],
"name": "Susceptibility Studies of Supercooled Liquids and Glasses",
"pagination": "259-283",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1010458859"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/978-94-011-1908-5_12"
]
}
],
"publisher": {
"name": "Springer Nature",
"type": "Organisation"
},
"sameAs": [
"https://doi.org/10.1007/978-94-011-1908-5_12",
"https://app.dimensions.ai/details/publication/pub.1010458859"
],
"sdDataset": "chapters",
"sdDatePublished": "2022-05-10T10:47",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/chapter/chapter_327.jsonl",
"type": "Chapter",
"url": "https://doi.org/10.1007/978-94-011-1908-5_12"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-94-011-1908-5_12'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-94-011-1908-5_12'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-94-011-1908-5_12'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-94-011-1908-5_12'
This table displays all metadata directly associated to this object as RDF triples.
125 TRIPLES
23 PREDICATES
86 URIs
79 LITERALS
7 BLANK NODES
Subject | Predicate | Object | |
---|---|---|---|
1 | sg:pub.10.1007/978-94-011-1908-5_12 | schema:about | anzsrc-for:03 |
2 | ″ | ″ | anzsrc-for:0306 |
3 | ″ | schema:author | Na2d47de10e1d454d82b7514001f1012f |
4 | ″ | schema:datePublished | 1993 |
5 | ″ | schema:datePublishedReg | 1993-01-01 |
6 | ″ | schema:description | These lectures review the results of a number of susceptibility studies of supercooled liquids and glasses. Dielectric response and specific-heat spectroscopy can investigate the motions that occur at the glass transition, Tg, as the liquid slows down and approaches an amorphous solid. In contrast to predictions of mode-coupling theory, these experiments give no evidence of a critical slowing down occurring at high temperature but rather indicate a divergence of the relaxation-time scales at a much lower value close to the Kauzmann temperature where the extrapolation of the entropy of the liquid state crosses that of the crystal. In addition, the dielectric relaxation of the liquid (for all temperatures and samples measured) can be scaled onto a single master curve. In addition to this primary relaxation, dielectric susceptibility can give detailed information about the secondary (Johari-Goldstein) relaxation occurring in the glass phase below Tg. For several glasses, the dielectric studies indicate that the secondary relaxation is due to the activation of single, uncoupled, entities over barriers which have a Gaussian distribution of energies. |
7 | ″ | schema:editor | Naa6c74e4d83e4936a1007a1e53d9031a |
8 | ″ | schema:genre | chapter |
9 | ″ | schema:inLanguage | en |
10 | ″ | schema:isAccessibleForFree | false |
11 | ″ | schema:isPartOf | N81d0bb33d3a94731b38126cc432957ea |
12 | ″ | schema:keywords | Gaussian distribution |
13 | ″ | ″ | Kauzmann temperature |
14 | ″ | ″ | Supercooled Liquids |
15 | ″ | ″ | Tg |
16 | ″ | ″ | activation |
17 | ″ | ″ | addition |
18 | ″ | ″ | amorphous solids |
19 | ″ | ″ | barriers |
20 | ″ | ″ | contrast |
21 | ″ | ″ | critical slowing |
22 | ″ | ″ | cross |
23 | ″ | ″ | crystals |
24 | ″ | ″ | curves |
25 | ″ | ″ | detailed information |
26 | ″ | ″ | dielectric relaxation |
27 | ″ | ″ | dielectric response |
28 | ″ | ″ | dielectric studies |
29 | ″ | ″ | dielectric susceptibility |
30 | ″ | ″ | distribution |
31 | ″ | ″ | divergence |
32 | ″ | ″ | energy |
33 | ″ | ″ | entities |
34 | ″ | ″ | entropy |
35 | ″ | ″ | evidence |
36 | ″ | ″ | experiments |
37 | ″ | ″ | extrapolation |
38 | ″ | ″ | glass |
39 | ″ | ″ | glass phase |
40 | ″ | ″ | glass transition |
41 | ″ | ″ | high temperature |
42 | ″ | ″ | information |
43 | ″ | ″ | lectures |
44 | ″ | ″ | liquid |
45 | ″ | ″ | lower values |
46 | ″ | ″ | master curve |
47 | ″ | ″ | mode-coupling theory |
48 | ″ | ″ | motion |
49 | ″ | ″ | number |
50 | ″ | ″ | phase |
51 | ″ | ″ | prediction |
52 | ″ | ″ | primary relaxation |
53 | ″ | ″ | relaxation |
54 | ″ | ″ | relaxation time scale |
55 | ″ | ″ | response |
56 | ″ | ″ | results |
57 | ″ | ″ | scale |
58 | ″ | ″ | secondary relaxation |
59 | ″ | ″ | single master curve |
60 | ″ | ″ | slowing |
61 | ″ | ″ | solids |
62 | ″ | ″ | specific heat spectroscopy |
63 | ″ | ″ | spectroscopy |
64 | ″ | ″ | state crosses |
65 | ″ | ″ | study |
66 | ″ | ″ | susceptibility |
67 | ″ | ″ | susceptibility studies |
68 | ″ | ″ | temperature |
69 | ″ | ″ | theory |
70 | ″ | ″ | transition |
71 | ″ | ″ | values |
72 | ″ | schema:name | Susceptibility Studies of Supercooled Liquids and Glasses |
73 | ″ | schema:pagination | 259-283 |
74 | ″ | schema:productId | N01212b12270448aaaa7828644b7d5ea6 |
75 | ″ | ″ | Nc819fdd1833c4066a6940e931bfe8270 |
76 | ″ | schema:publisher | N323f4c1909394730ab2f6c997b71fc24 |
77 | ″ | schema:sameAs | https://app.dimensions.ai/details/publication/pub.1010458859 |
78 | ″ | ″ | https://doi.org/10.1007/978-94-011-1908-5_12 |
79 | ″ | schema:sdDatePublished | 2022-05-10T10:47 |
80 | ″ | schema:sdLicense | https://scigraph.springernature.com/explorer/license/ |
81 | ″ | schema:sdPublisher | N38073d7510c740a79fb433d7f9548885 |
82 | ″ | schema:url | https://doi.org/10.1007/978-94-011-1908-5_12 |
83 | ″ | sgo:license | sg:explorer/license/ |
84 | ″ | sgo:sdDataset | chapters |
85 | ″ | rdf:type | schema:Chapter |
86 | N01212b12270448aaaa7828644b7d5ea6 | schema:name | doi |
87 | ″ | schema:value | 10.1007/978-94-011-1908-5_12 |
88 | ″ | rdf:type | schema:PropertyValue |
89 | N1d610b5ffcb74fc193f868fdf42ba70a | rdf:first | N4071659b96cb4c1785dce0f34c29f277 |
90 | ″ | rdf:rest | rdf:nil |
91 | N323f4c1909394730ab2f6c997b71fc24 | schema:name | Springer Nature |
92 | ″ | rdf:type | schema:Organisation |
93 | N38073d7510c740a79fb433d7f9548885 | schema:name | Springer Nature - SN SciGraph project |
94 | ″ | rdf:type | schema:Organization |
95 | N4071659b96cb4c1785dce0f34c29f277 | schema:familyName | Sherrington |
96 | ″ | schema:givenName | David |
97 | ″ | rdf:type | schema:Person |
98 | N81d0bb33d3a94731b38126cc432957ea | schema:isbn | 978-94-010-4843-9 |
99 | ″ | ″ | 978-94-011-1908-5 |
100 | ″ | schema:name | Phase Transitions and Relaxation in Systems with Competing Energy Scales |
101 | ″ | rdf:type | schema:Book |
102 | Na2d47de10e1d454d82b7514001f1012f | rdf:first | sg:person.0727503755.14 |
103 | ″ | rdf:rest | rdf:nil |
104 | Na607ecef8f4741b695fa35682a592378 | schema:familyName | Riste |
105 | ″ | schema:givenName | Tormod |
106 | ″ | rdf:type | schema:Person |
107 | Naa6c74e4d83e4936a1007a1e53d9031a | rdf:first | Na607ecef8f4741b695fa35682a592378 |
108 | ″ | rdf:rest | N1d610b5ffcb74fc193f868fdf42ba70a |
109 | Nc819fdd1833c4066a6940e931bfe8270 | schema:name | dimensions_id |
110 | ″ | schema:value | pub.1010458859 |
111 | ″ | rdf:type | schema:PropertyValue |
112 | anzsrc-for:03 | schema:inDefinedTermSet | anzsrc-for: |
113 | ″ | schema:name | Chemical Sciences |
114 | ″ | rdf:type | schema:DefinedTerm |
115 | anzsrc-for:0306 | schema:inDefinedTermSet | anzsrc-for: |
116 | ″ | schema:name | Physical Chemistry (incl. Structural) |
117 | ″ | rdf:type | schema:DefinedTerm |
118 | sg:person.0727503755.14 | schema:affiliation | grid-institutes:grid.170205.1 |
119 | ″ | schema:familyName | Nagel |
120 | ″ | schema:givenName | Sidney R. |
121 | ″ | schema:sameAs | https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0727503755.14 |
122 | ″ | rdf:type | schema:Person |
123 | grid-institutes:grid.170205.1 | schema:alternateName | The James Franck Institute and The Department of Physics, The University of Chicago, 5640 South Ellis Avenue, 60637, Chicago, Illinois, USA |
124 | ″ | schema:name | The James Franck Institute and The Department of Physics, The University of Chicago, 5640 South Ellis Avenue, 60637, Chicago, Illinois, USA |
125 | ″ | rdf:type | schema:Organization |