The Reorientational Dynamics in Liquid Methanol View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1994

AUTHORS

T. Bultmann , K. Kemeter , Ch. Rusbüldt , Ph. A. Bopp , N. P. Ernsting

ABSTRACT

The results from nuclear magnetic resonance (NMR) relaxation time measurements, time resolved ultrafast spectroscopy and classical molecular dynamics (MD) computer simulations are combined to yield a detailed understanding of the reorientational dynamics in liquid methanol (CH3OH) at room temperature. It is found that the reorientational motions of single molecules are anisotropic, the correlation times for molecule-fixed vectors perpendicular to the H-bond is about half that for the O-H vector. Furthermore, the dielectric relaxation of methanol after strong perturbation was measured to be temperature dependent. More... »

PAGES

383-391

Book

TITLE

Reaction Dynamics in Clusters and Condensed Phases

ISBN

978-94-010-4337-3
978-94-011-0786-0

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-94-011-0786-0_26

DOI

http://dx.doi.org/10.1007/978-94-011-0786-0_26

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044831394


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