Reactions of Silylalkynes with Triosmium and Triruthenium Clusters View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1995

AUTHORS

A. A. Koridze

ABSTRACT

Our continuing interest in transformations of heteroatom-substituted alkynes on transition metal clusters [1,2] has prompted us to investigate reactions of silylalkynes with triruthenium and triosmium clusters.It should be noted that reactions of silylalkynes with metal clusters have earlier been studied by several groups but these alkynes did not reveal any unusual reactivity. We observed, however, unusual transformations of silylalkynes on triruthenium and triosmium clusters, metal complexes bearing novel organic ligands, and novel rearrangements. These findings are the subject of the present report. More... »

PAGES

351-360

Book

TITLE

The Synergy Between Dynamics and Reactivity at Clusters and Surfaces

ISBN

978-94-010-4060-0
978-94-011-0133-2

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-94-011-0133-2_23

DOI

http://dx.doi.org/10.1007/978-94-011-0133-2_23

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011434695


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