Iron Uniform-Size Nanoparticles Dispersed on MCM-41 Used as Hydrocarbon Synthesis Catalyst View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2002

AUTHORS

S. G. Marchetti , M. V. Cagnoli , A. M. Alvarez , J. F. Bengoa , N. G. Gallegos , A. A. Yeramián , R. C. Mercader

ABSTRACT

We have synthesized mesoporous MCM-41 and have used it as a support for iron particles to be employed as a catalyst in the Fischer-Tropsch reaction. The solids were characterized by Mössbauer spectroscopy, X-ray diffraction, BET, TGA, CO chemisorption and volumetric oxidation. Although the catalyst showed a high CO conversion when it was used in the hydrocarbon synthesis from CO and H2 (14.3% at 1 h of reaction time) mainly methane was formed. The high methane production is likely related to the very small size of the metal particles obtained. We suggest some ways to improve the selectivity. More... »

PAGES

33-40

Book

TITLE

Industrial Applications of the Mössbauer Effect

ISBN

978-94-010-3950-5
978-94-010-0299-8

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-94-010-0299-8_3

DOI

http://dx.doi.org/10.1007/978-94-010-0299-8_3

DIMENSIONS

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141 https://www.grid.ac/institutes/grid.9499.d schema:alternateName National University of La Plata
142 schema:name Centro de Investigación y Desarrollo en Procesos Catalíticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900 La Plata, Argentina
143 Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900 La Plata, Argentina
144 Departamento de Química, Facultad de Ingeniería, Universidad Nacional de La Plata, 47 115, 1900 La Plata, Argentina
145 rdf:type schema:Organization
 




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