Analysis of Reaction Products of Propellants and High Explosives View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1990

AUTHORS

F. Volk

ABSTRACT

The reaction products of propellants and high explosives are dependent on the pressure and therefore also on the confinement under which the combustion or detonation reaction proceeds. In order to evaluate this influence, different propellants were burned under atmospheric pressure and heavy confinement in a closed vessel.In addition, high explosives containing TNT were initiated in an evacuated metal container under an atmosphere of argon. In all cases, the products were analyzed to find out the completeness of the combustion and detonation reaction. The gaseous products were analyzed by mass spectrometry and gas-chromatography, the residues by CHN-analysis and high performance liquid chromatography. The combustion of propellants at atmospheric pressure formed incomplete reaction gases with a high content of NO.The investigation of the detonation products of unconfined high explosives has shown that unreacted TNT could be found in the solid residue and analyzed when the initiating booster was not optimized. More... »

PAGES

511-523

Book

TITLE

Chemistry and Physics of Energetic Materials

ISBN

978-94-010-7413-1
978-94-009-2035-4

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-94-009-2035-4_22

DOI

http://dx.doi.org/10.1007/978-94-009-2035-4_22

DIMENSIONS

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