1988
AUTHORSZoran S. Petrović , William J. MacKnight , Ronald Koningsveld , Karel Dušek
ABSTRACTAn approach is proposed for the treatment of equilibrium swelling of networks obtained by crosslinking polypropylene glycol (PPG) chains with a triisocyanate crosslinker, ‘Desmodur RF’ (DRF). Three models are used for the analysis of swelling of these polyurethane networks in toluene and methanol. It is shown that the χ parameter of the copolymer network depends on the interactions between the solvent and the individual components of the network and between these components themselves. Swelling data in methanol and toluene appear to yield the same value for the interaction parameter of the network components provided a) the differences in molecular surface area between the various building blocks of the systems and b) the molecular association of methanol are taken into account. Two networks, identical in number average chain length between crosslinks but differing in chain length distribution, have Identical enthalpic contributions to the effective interaction parameter but different entropic terms. The conclusions are affected neither by the choice of the model used for the front factors nor by possibly necessary corrections for the number of elastically active network chains. A simple solubility parameter treatment provides a fair prediction of swelling in mixtures of methanol and toluene. More... »
PAGES269-282
Integration of Fundamental Polymer Science and Technology—2
ISBN
978-94-010-7106-2
978-94-009-1361-5
http://scigraph.springernature.com/pub.10.1007/978-94-009-1361-5_41
DOIhttp://dx.doi.org/10.1007/978-94-009-1361-5_41
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1004892450
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0104",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Statistics",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/01",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Mathematical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Novi Sad",
"id": "https://www.grid.ac/institutes/grid.10822.39",
"name": [
"Faculty of Technology, University of Novi Sad, Yugoslavia"
],
"type": "Organization"
},
"familyName": "Petrovi\u0107",
"givenName": "Zoran S.",
"id": "sg:person.014744722141.41",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014744722141.41"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Massachusetts Amherst",
"id": "https://www.grid.ac/institutes/grid.266683.f",
"name": [
"Polymer Sci.& Eng. Dep, Univ. of Massachusetts, 01003, Amherst, MA, USA"
],
"type": "Organization"
},
"familyName": "MacKnight",
"givenName": "William J.",
"id": "sg:person.014451527037.72",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014451527037.72"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Massachusetts Amherst",
"id": "https://www.grid.ac/institutes/grid.266683.f",
"name": [
"Polymer Sci.& Eng. Dep, Univ. of Massachusetts, 01003, Amherst, MA, USA"
],
"type": "Organization"
},
"familyName": "Koningsveld",
"givenName": "Ronald",
"id": "sg:person.011131430636.71",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011131430636.71"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Academy of Sciences of the Czech Republic",
"id": "https://www.grid.ac/institutes/grid.418095.1",
"name": [
"Inst. Macromol.Chem., Czechoslovak Acad. Sci., 16206, Prague 6, Czech Republic"
],
"type": "Organization"
},
"familyName": "Du\u0161ek",
"givenName": "Karel",
"id": "sg:person.01151570140.64",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/0032-3861(83)90148-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002937764"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(83)90148-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002937764"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1098/rspa.1976.0146",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003003881"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1524/zpch.1958.16.3_6.292",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018491420"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/polb.1986.090240401",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021195201"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(84)90207-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022119046"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(84)90207-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022119046"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980090215",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025415843"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980090215",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025415843"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bfb0114008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025764504",
"https://doi.org/10.1007/bfb0114008"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bfb0114008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025764504",
"https://doi.org/10.1007/bfb0114008"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bfb0051042",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029895882",
"https://doi.org/10.1007/bfb0051042"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pol.1955.120168236",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034887209"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/recl.19370560908",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044301255"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/recl.19370560908",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044301255"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.5254/1.3535867",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1049802367"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/recl.19410600202",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053185042"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/recl.19410600202",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053185042"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/j100785a001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055677944"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00140a026",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056179669"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00144a022",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056179911"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00153a021",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056180339"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00155a013",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056180478"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00239a010",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056185095"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00246a006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056185304"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1723792",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057790666"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1723938",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057790812"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1747424",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057809590"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1750930",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057812860"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1750971",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057812901"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.447237",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1058025257"
],
"type": "CreativeWork"
}
],
"datePublished": "1988",
"datePublishedReg": "1988-01-01",
"description": "An approach is proposed for the treatment of equilibrium swelling of networks obtained by crosslinking polypropylene glycol (PPG) chains with a triisocyanate crosslinker, \u2018Desmodur RF\u2019 (DRF). Three models are used for the analysis of swelling of these polyurethane networks in toluene and methanol. It is shown that the \u03c7 parameter of the copolymer network depends on the interactions between the solvent and the individual components of the network and between these components themselves. Swelling data in methanol and toluene appear to yield the same value for the interaction parameter of the network components provided a) the differences in molecular surface area between the various building blocks of the systems and b) the molecular association of methanol are taken into account. Two networks, identical in number average chain length between crosslinks but differing in chain length distribution, have Identical enthalpic contributions to the effective interaction parameter but different entropic terms. The conclusions are affected neither by the choice of the model used for the front factors nor by possibly necessary corrections for the number of elastically active network chains. A simple solubility parameter treatment provides a fair prediction of swelling in mixtures of methanol and toluene.",
"editor": [
{
"familyName": "Lemstra",
"givenName": "P. J.",
"type": "Person"
},
{
"familyName": "Kleintjens",
"givenName": "L. A.",
"type": "Person"
}
],
"genre": "chapter",
"id": "sg:pub.10.1007/978-94-009-1361-5_41",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": {
"isbn": [
"978-94-010-7106-2",
"978-94-009-1361-5"
],
"name": "Integration of Fundamental Polymer Science and Technology\u20142",
"type": "Book"
},
"name": "Thermodynamics Of Swelling Of Model Networks",
"pagination": "269-282",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1004892450"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/978-94-009-1361-5_41"
]
},
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"17501b8b9965cf4e1ad70e2788cafe1cc98ea477ddf4288dd0492d1b1f7b219d"
]
}
],
"publisher": {
"location": "Dordrecht",
"name": "Springer Netherlands",
"type": "Organisation"
},
"sameAs": [
"https://doi.org/10.1007/978-94-009-1361-5_41",
"https://app.dimensions.ai/details/publication/pub.1004892450"
],
"sdDataset": "chapters",
"sdDatePublished": "2019-04-16T09:33",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000373_0000000373/records_13073_00000000.jsonl",
"type": "Chapter",
"url": "https://link.springer.com/10.1007%2F978-94-009-1361-5_41"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1361-5_41'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1361-5_41'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1361-5_41'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1361-5_41'
This table displays all metadata directly associated to this object as RDF triples.
174 TRIPLES
23 PREDICATES
52 URIs
20 LITERALS
8 BLANK NODES