Ontology type: schema:Chapter
1988
AUTHORS ABSTRACTThe curing of N-N-diglycidylaniline (DGA) and N,N,N′,N′-tetraglycidyl-diaminodiphenylmethane with polyamines differs from that of diglycidyl ether of hisphenol-A by a high tendency to cyclization and by interdependence of reactivities of the glycidyl groups bound to the same nitrogen atom. Cyclization is characterized by formation of small cycles by intramolecular epoxy-amine addition or etherification. The reaction of the monoadduct of DGA and a secondary amine bearing another epoxy group with another secondary amine molecule is considerably faster than that of DGA with the same secondary amine. This feature is explained by intramolecular catalysis of the addition by the OH group in the monoadduct. The interplay of the substitution effects in the amine group and in DGA as reflected in gelation is complex, however. The development of a statistical branching theory taking these features into account is outlined. More... »
PAGES335-344
Biological and Synthetic Polymer Networks
ISBN
978-94-010-7097-3
978-94-009-1343-1
http://scigraph.springernature.com/pub.10.1007/978-94-009-1343-1_22
DOIhttp://dx.doi.org/10.1007/978-94-009-1343-1_22
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1032889188
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0101",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Pure Mathematics",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/01",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Mathematical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Institute of Macromolecular Chemistry",
"id": "https://www.grid.ac/institutes/grid.424999.b",
"name": [
"Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06, Prague, Czechoslovakia"
],
"type": "Organization"
},
"familyName": "Du\u0161ek",
"givenName": "Karel",
"id": "sg:person.01151570140.64",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151570140.64"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Macromolecular Chemistry",
"id": "https://www.grid.ac/institutes/grid.424999.b",
"name": [
"Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06, Prague, Czechoslovakia"
],
"type": "Organization"
},
"familyName": "Mat\u011bjka",
"givenName": "Libor",
"id": "sg:person.013325554553.39",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013325554553.39"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1002/pol.1977.170151009",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009734713"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00262114",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1010004441",
"https://doi.org/10.1007/bf00262114"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00262114",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1010004441",
"https://doi.org/10.1007/bf00262114"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/3-540-15546-5_1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014569225",
"https://doi.org/10.1007/3-540-15546-5_1"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/3-540-15546-5_1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014569225",
"https://doi.org/10.1007/3-540-15546-5_1"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980090214",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020289758"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980090214",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020289758"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bfb0017916",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026487317",
"https://doi.org/10.1007/bfb0017916"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00265719",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030485869",
"https://doi.org/10.1007/bf00265719"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00265719",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030485869",
"https://doi.org/10.1007/bf00265719"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980170218",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033332614"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pi.4980170218",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033332614"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bfb0035356",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034027589",
"https://doi.org/10.1007/bfb0035356"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00708469",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043885188",
"https://doi.org/10.1007/bf00708469"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00708469",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043885188",
"https://doi.org/10.1007/bf00708469"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00708469",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043885188",
"https://doi.org/10.1007/bf00708469"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00229a018",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056184613"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00254954",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1085143650",
"https://doi.org/10.1007/bf00254954"
],
"type": "CreativeWork"
}
],
"datePublished": "1988",
"datePublishedReg": "1988-01-01",
"description": "The curing of N-N-diglycidylaniline (DGA) and N,N,N\u2032,N\u2032-tetraglycidyl-diaminodiphenylmethane with polyamines differs from that of diglycidyl ether of hisphenol-A by a high tendency to cyclization and by interdependence of reactivities of the glycidyl groups bound to the same nitrogen atom. Cyclization is characterized by formation of small cycles by intramolecular epoxy-amine addition or etherification. The reaction of the monoadduct of DGA and a secondary amine bearing another epoxy group with another secondary amine molecule is considerably faster than that of DGA with the same secondary amine. This feature is explained by intramolecular catalysis of the addition by the OH group in the monoadduct. The interplay of the substitution effects in the amine group and in DGA as reflected in gelation is complex, however. The development of a statistical branching theory taking these features into account is outlined.",
"editor": [
{
"familyName": "Kramer",
"givenName": "O.",
"type": "Person"
}
],
"genre": "chapter",
"id": "sg:pub.10.1007/978-94-009-1343-1_22",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": {
"isbn": [
"978-94-010-7097-3",
"978-94-009-1343-1"
],
"name": "Biological and Synthetic Polymer Networks",
"type": "Book"
},
"name": "Special Features of Network Build-Up in Curing of Polyepoxides Based on N,N-Diglycidylaniline Derivatives",
"pagination": "335-344",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1032889188"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/978-94-009-1343-1_22"
]
},
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"9cae4bf765b53f553ed68b3070b609076470edef6993f39c13ce354d4c1c1d0d"
]
}
],
"publisher": {
"location": "Dordrecht",
"name": "Springer Netherlands",
"type": "Organisation"
},
"sameAs": [
"https://doi.org/10.1007/978-94-009-1343-1_22",
"https://app.dimensions.ai/details/publication/pub.1032889188"
],
"sdDataset": "chapters",
"sdDatePublished": "2019-04-16T09:33",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000373_0000000373/records_13069_00000001.jsonl",
"type": "Chapter",
"url": "https://link.springer.com/10.1007%2F978-94-009-1343-1_22"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1343-1_22'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1343-1_22'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1343-1_22'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-94-009-1343-1_22'
This table displays all metadata directly associated to this object as RDF triples.
112 TRIPLES
23 PREDICATES
38 URIs
20 LITERALS
8 BLANK NODES