Across the Periodic Table View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1994

AUTHORS

C. Bréchignac , M. F. Jarrold , E. E. B. Campbell , T. P. Martin , H. Haberland , U. Buck

ABSTRACT

Because of the freely mobile electrons the alkali metals are often considered as prototypes of metals well described with the free electron methods. In connection with that alkali clusters are also considered as prototypes of metals clusters. However the applicability of methods based on concepts well proven in solid state physics can start to be questionable when a cluster is very small. Going from atom to the bulk the question is from what cluster size the electronic properties of alkali clusters can be described with the free electron model? Moreover how does the quantum size effect affect their electronic structure? On the other hand how can notions such as surface tension or surface curvature be employed to interpret deviation from bulk properties concerning ionization potentials or binding energies per atom? More... »

PAGES

253-418

Book

TITLE

Clusters of Atoms and Molecules

ISBN

978-3-642-84331-0
978-3-642-84329-7

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-642-84329-7_4

DOI

http://dx.doi.org/10.1007/978-3-642-84329-7_4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036637707


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