Shell structure of electronic states of Cu clusters View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1989

AUTHORS

T. Yamaguchi , N. Fujima

ABSTRACT

Electronic states of icosahedral Cu13 and Cu12 clusters were calculated by the DV-Xα method which took into account of many-electron effects. The valence 3uid orbitals are localized within atom and isolated from the valence 4s orbitals extended over the whole cluster. The characteristic feature of the states of s valence electrons of Cu13 cluster well corresponds to that of one-electron picture i.e. the shell model of the 3-dimensional isotropic harmonic oscillator potential. Electronic states of valence levels of Cu12 cluster which have no central atom fairly well correspond to those of a combined potential of the harmonic oscillator and a 3-dimensional Gaussian potential barrier at the center of the cluster. More... »

PAGES

369-371

Book

TITLE

Small Particles and Inorganic Clusters

ISBN

978-3-642-74915-5
978-3-642-74913-1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-642-74913-1_82

DOI

http://dx.doi.org/10.1007/978-3-642-74913-1_82

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018261765


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