Inelastic Neutron Scattering Study of Methyl Tunnelling in α-Crystallised Toluene View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1987

AUTHORS

D. Cavagnat , A. Magerl , C. Vettier , S. Clough

ABSTRACT

A considerable amount of information was collected over recent years about rotational dynamics of the methyl group in molecular crystals by using principally N.M.R. and neutron scattering techniques. This latter method is particularly powerful for the low rotational barrier cases by providing a complete level scheme in a large temperature and pressure range. Combining these results with precise structural data, a good determination of the potential energy function and of the responsible intermolecular forces may be reached, as illustrated recently with the nitromethane study /1–3/. More... »

PAGES

24-27

Book

TITLE

Quantum Aspects of Molecular Motions in Solids

ISBN

978-3-642-71916-5
978-3-642-71914-1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-642-71914-1_4

DOI

http://dx.doi.org/10.1007/978-3-642-71914-1_4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037728958


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