The Influence of Electrons on the Tunneling State of a Hydrogen Atom in a Metal View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1987

AUTHORS

H. Wipf , D. Steinbinder , K. Neumaier , P. Gutsmiedl , A. Magerl , A. J. Dianoux

ABSTRACT

The thermal destruction of a tunneling state in a molecular crystal, which becomes observable in a neutron spectroscopic experiment say above 10 K, is generally attributed to interactions with phonons. If the tunnel system is in a metallic environment there is an additional relaxation path originating from the interaction with electrons. We have studied by inelastic neutron scattering the tunneling of a single proton in Nb(OH)x with x = 0.002 and x = 0.0002 from 0.1 to 10 K in both a superconducting and a normal conducting environment (applied magnetic field 0.7 T). These data show that the interaction of the H tunnel state with conduction electrons dominates the observed damping in this temperature range. In addition, different values for the tunnel splitting are found in the superconducting state (Js = 226 μeV) and in the normal conducting state (JN = 206 μeV). This renormalisation and the damping are described consistently by only one coupling parameter K = 0.053. More... »

PAGES

153-157

Book

TITLE

Quantum Aspects of Molecular Motions in Solids

ISBN

978-3-642-71916-5
978-3-642-71914-1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-642-71914-1_26

DOI

http://dx.doi.org/10.1007/978-3-642-71914-1_26

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003764139


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