Alumoxanes alternative to MAO: Synthesis and characterization View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1999

AUTHORS

T. Dall’Occo , M. Galimberti , I. Camurati , M. Destro , O. Fusco , D. Brita

ABSTRACT

A new alumoxane alternative to MAO was synthesised, characterized and used as cocatalyst for metallocene based polymerizations. It is based on Al(2,4,4-trimethylpentyl)3 (TIOA). Alumoxanes were prepared by reacting TIOA and H2O with different molar ratios. 1H NMR spectra of these products are characterized by the presence of broad bands and of resolved multiplets. Their relative amount in the region between 1.9 and 2.5 ppm was identified as the “finger-print” of the polymerization activity. More... »

PAGES

142-149

Book

TITLE

Metalorganic Catalysts for Synthesis and Polymerization

ISBN

978-3-642-64292-0
978-3-642-60178-1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-642-60178-1_14

DOI

http://dx.doi.org/10.1007/978-3-642-60178-1_14

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042733545


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