Complex Formation of Uranium(IV) with Phosphate and Arsenate View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2002

AUTHORS

G. Geipel , G. Bernhard , V. Brendler

ABSTRACT

We studied the complex formation of uranium(IV) with phosphate and arsenate in acid solution using UV-VIS and laser-induced photo-acoustic spectroscopy at various ionic strengths. We found a one to one complex formation between uranium and phosphoric acid and arsenic acid, respectively. During the complex forming reaction one hydrogen ion was released from the acid. Including the protonation constants of the used acids at infinite dilution, the formation constants were derived to be log (β0121 = 25.23 ± 0.13 for the phosphate system and log β0121 = 23.94 ± 0.08 for the arsenate system, respectively. More... »

PAGES

369-376

References to SciGraph publications

  • 2000. Speciation in Water Released from Mining and Milling Facilities in THE ENVIRONMENTAL CHALLENGES OF NUCLEAR DISARMAMENT
  • Book

    TITLE

    Uranium in the Aquatic Environment

    ISBN

    978-3-642-62877-1
    978-3-642-55668-5

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-3-642-55668-5_42

    DOI

    http://dx.doi.org/10.1007/978-3-642-55668-5_42

    DIMENSIONS

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