Uranium(VI) Sulfate Complexation as a Function of Temperature and Ionic Strength Studied by TRLFS View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2008

AUTHORS

Aleš Vetešník , Miroslava Semelová , Karel Štamberg , Dušan Vopálka

ABSTRACT

Time-resolved laser-induced fluorescence spectroscopy (TRLFS) was used to direct study of uranium(VI)-sulfate complexation. By varying sulfate concentration (4x10-4 – 7.5x10-1 M) at fixed pH (= 2), uranium concentration (=1x10-5 M) and ionic strength (= 1), we were able to identify, as well as to quantify all relevant uranium-sulfate complexes, at two temperatures (293.15 and 298.15 K). The corresponding stability constants were estimated from the measured species distribution. The estimated stability constants are in relatively good agreement with the values derived from the literature. More... »

PAGES

623-630

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-540-87746-2_78

DOI

http://dx.doi.org/10.1007/978-3-540-87746-2_78

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043877174


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