Spectroscopic study of the uranium(IV) complexation by organic model ligands in aqueous solution View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2008

AUTHORS

Katja Schmeide , Gert Bernhard

ABSTRACT

The complexation of uranium(IV) with the organic model ligands citric acid, succinic acid and mandelic acid has been investigated in dependence on acidity (0.1 M to 1.0 M) and ionic strength (0.11 M to 1.0 M) by UV-Vis spectroscopy. In the citrate media, the formation of 1:1 and 1:2 complexes was detected. The stability constants for 1:1 and 1:2 uranium(IV) citrate complexes of the type MpHqLr were determined with log β101 = 13.5 ± 0.2 and log β102 = 25.1 ± 0.2. The stability constants determined for the complexation of uranium(IV) with succinic acid and mandelic acid are lower. More... »

PAGES

591-598

References to SciGraph publications

  • 2000. Speciation in Water Released from Mining and Milling Facilities in THE ENVIRONMENTAL CHALLENGES OF NUCLEAR DISARMAMENT
  • Book

    TITLE

    Uranium, Mining and Hydrogeology

    ISBN

    978-3-540-87745-5
    978-3-540-87746-2

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-3-540-87746-2_73

    DOI

    http://dx.doi.org/10.1007/978-3-540-87746-2_73

    DIMENSIONS

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