Thermodynamical Data of uranyl carbonate complexes from Absorption Spectroscopy View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2008

AUTHORS

Christian Götz , Gerhard Geipel , Gert Bernhard

ABSTRACT

Aquatic uranyl carbonate complexes play an important role in the hydrogeology of uranium mining areas and nuclear waste disposals. Many publications are available for the stability of uranyl carbonate complexes, but thermodynamical data like the enthalpy or entropy are rare. We determined thermodynamical data from spectroscopic studies for the uranyl carbonate complex UO2(CO3)34- in the temperature range from 5 °C to 70 °C. The reaction enthalpy the reaction entropy were determined to be -36.25 ± 4.31 kJ/mol and 297.082 ± 13.839 J/(K∙mol), respectively. More... »

PAGES

907-914

References to SciGraph publications

Book

TITLE

Uranium, Mining and Hydrogeology

ISBN

978-3-540-87745-5
978-3-540-87746-2

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-540-87746-2_118

DOI

http://dx.doi.org/10.1007/978-3-540-87746-2_118

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018300697


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