Formation of Mn-doped iron silicides by ball milling View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2006-12-19

AUTHORS

J. Desimoni , S. M. Cotes , M. A. Taylor , R. C. Mercader

ABSTRACT

Using X-ray diffraction (XRD) and Mossbauer spectroscopy, we have studied the sequence of phase formations in the solid Mn-doped iron silicide series Fel−xMnxSi2, with 0.00≤sx≤0.12, in samples prepared by mechanical alloying from the pure elements. The milling was carried out at room temperature in Ar atmosphere in a horizontal mill for 15 h. The XRD patterns display broad lines, which can be ascribed to stable and metastable iron silicides like β-FeSi2, ε-FeSi, α-FeSi2, MnSi, and Si. The set of hyperfine parameters obtained support the coexistence of β-FeSi2, α-FeSi2 and α-FeSi, in agreement with the XRD results. No replacement of Fe by Mn atoms in the regular sites of β-FeSi2 has been observed. More... »

PAGES

959-964

References to SciGraph publications

Book

TITLE

ICAME 2005

ISBN

978-3-540-49852-0
978-3-540-49853-7

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-540-49853-7_42

DOI

http://dx.doi.org/10.1007/978-3-540-49853-7_42

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016165146


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