Chemical reduction of hematite by sodium borohydride View Full Text


Ontology type: schema:Chapter      Open Access: True


Chapter Info

DATE

2006-10-26

AUTHORS

V. G. de Resende , G. M. da Costa , E. De Grave , L. Datas

ABSTRACT

Well-crystallized hematite was suspended in water and treated at room-temperature (RT) with sodium borohydride. The product of the reaction is a highly magnetic black powder, which is stable at RT. The NaBH4 treatment converts about half of the hematite to an amorphous Fe-B alloy and to a small fraction of sub-micron sized, amorphous metallic-Fe nodules. Heating at 400°C of this composite has resulted in the crystallization and/or oxidation of more than half of the amorphous Fe-B phase to α-Fe and Fe3O4 and B2O3, respectively. After treatment at 800°C, the metallic Fe and the amorphous Fe-B have completely vanished, and the resulting product consists of hematite and FeBO3 embedded in the matrix of α-Fe2O3. More... »

PAGES

113-119

References to SciGraph publications

Book

TITLE

ICAME 2005

ISBN

978-3-540-49848-3
978-3-540-49850-6

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-540-49850-6_16

DOI

http://dx.doi.org/10.1007/978-3-540-49850-6_16

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008820596


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