Optical Anisotropy and Compositional Ratio of Conductive Polymer PEDOT:PSS and Their Effect on Photovoltaic Performance of Crystalline Silicon/Organic Heterojunction Solar ... View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2018

AUTHORS

Hajime Shirai , Qiming Liu , Tatsuya Ohki , Ryo Ishikawa , Keiji Ueno

ABSTRACT

We demonstrate the optical anisotropy of a transparent conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and its effect on the photovoltaic performance of n-type crystalline silicon (n-Si)/PEDOT:PSS heterojunction solar cells. The depth profile of PEDOT/PSS compositional ratio and optical anisotropy depends on the type of polar solvent and/or external DC bias supplied to n-Si substrate during film deposition by spin coating (SC) and chemical mist deposition (CMD). N-Si/PEDOT:PSS heterojunction solar cells with higher PEDOT/PSS compositional ratio near the film surface exhibited better power conversion efficiency η of 12.5% (@2 × 2 cm2) without any light harvesting techniques. In this chapter, the correlation among the optical anisotropy, the depth profile of PEDOT/PSS compositional ratio in conductive polymer PEDOT:PSS, and the photovoltaic performance of n-Si/PEDOT:PSS heterojunction solar cells is demonstrated. More... »

PAGES

137-159

References to SciGraph publications

  • 1973. Polymer Chemistry in NONE
  • Book

    TITLE

    Advances in Silicon Solar Cells

    ISBN

    978-3-319-69702-4
    978-3-319-69703-1

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-3-319-69703-1_5

    DOI

    http://dx.doi.org/10.1007/978-3-319-69703-1_5

    DIMENSIONS

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