Ontology type: schema:Chapter
2017
AUTHORSKarel Dušek , Jos Huybrechts , Miroslava Dušková-Smrčková
ABSTRACTPrecursors of cross-linked polymer systems are blends of many compounds, some of them forming series (distributions) of compounds of increasing molecular weights, type and number of functional groups, or some other property. The distributions may arise from impurities in the raw materials, or a result of side reactions. In most cases, the distributions are generated intentionally; functional copolymers, hyperbranched polymers, off-stoichiometric highly branched polymers, chain extended systems, or precursors prepared in several stages can serve as examples. The distributions affect processing and materials properties. We show ways to generate these distributions from bond formation kinetics and reaction mechanisms. Statistical branching theories based on assemblage of branched molecules and gel structure from building units in different reaction states are used to model the evolution of the cross-linked system. More... »
PAGES3-37
Protective Coatings
ISBN
978-3-319-51625-7
978-3-319-51627-1
http://scigraph.springernature.com/pub.10.1007/978-3-319-51627-1_1
DOIhttp://dx.doi.org/10.1007/978-3-319-51627-1_1
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