Ontology type: schema:Chapter
2016
AUTHORSIlaria D’Acquarica , Francesca Ghirga , Cinzia Ingallina , Deborah Quaglio , Giovanni Zappia , Gloria Uccello-Barretta , Federica Balzano , Bruno Botta
ABSTRACTThis chapter is aimed at providing an overview of the up-to-now published literature on resorc[4]arene macrocycles exploited as artificial receptors for surface recognition and host-guest chemistry. A concise illustration of the main synthetic strategies developed to afford the resorc[4]arene scaffold is followed by a report on the principles of the investigation of recognition phenomena by nuclear magnetic resonance (NMR), in particular the study of protein-small molecule interactions. Emphasis will be placed on the literature taken largely from our own works on the inhibition of chymotrypsin by suitable N-linked peptidoresorc[4]arenes. Then, the attention was moved towards host-guest studies relying on the entrapment of nitrosonium (NO+) cation inside the cavities of ad hoc functionalized resorc[4]arenes, which yielded both complexes and covalent products. Finally, some recent intriguing resorc[4]arene architectures built up by olefin metathesis reaction occurring between side chains ending with vinylidene groups are presented. More... »
PAGES175-193
Calixarenes and Beyond
ISBN
978-3-319-31865-3
978-3-319-31867-7
http://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8
DOIhttp://dx.doi.org/10.1007/978-3-319-31867-7_8
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curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8'
This table displays all metadata directly associated to this object as RDF triples.
282 TRIPLES
23 PREDICATES
76 URIs
20 LITERALS
8 BLANK NODES