Resorc[4]arenes as Preorganized Synthons for Surface Recognition and Host-Guest Chemistry View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2016

AUTHORS

Ilaria D’Acquarica , Francesca Ghirga , Cinzia Ingallina , Deborah Quaglio , Giovanni Zappia , Gloria Uccello-Barretta , Federica Balzano , Bruno Botta

ABSTRACT

This chapter is aimed at providing an overview of the up-to-now published literature on resorc[4]arene macrocycles exploited as artificial receptors for surface recognition and host-guest chemistry. A concise illustration of the main synthetic strategies developed to afford the resorc[4]arene scaffold is followed by a report on the principles of the investigation of recognition phenomena by nuclear magnetic resonance (NMR), in particular the study of protein-small molecule interactions. Emphasis will be placed on the literature taken largely from our own works on the inhibition of chymotrypsin by suitable N-linked peptidoresorc[4]arenes. Then, the attention was moved towards host-guest studies relying on the entrapment of nitrosonium (NO+) cation inside the cavities of ad hoc functionalized resorc[4]arenes, which yielded both complexes and covalent products. Finally, some recent intriguing resorc[4]arene architectures built up by olefin metathesis reaction occurring between side chains ending with vinylidene groups are presented. More... »

PAGES

175-193

References to SciGraph publications

  • 2014-02. NMR-based analysis of protein–ligand interactions in ANALYTICAL AND BIOANALYTICAL CHEMISTRY
  • 2006-03. Nitrosonium complexes of [2.2]paracyclophane in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • Book

    TITLE

    Calixarenes and Beyond

    ISBN

    978-3-319-31865-3
    978-3-319-31867-7

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-3-319-31867-7_8

    DOI

    http://dx.doi.org/10.1007/978-3-319-31867-7_8

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1049916181


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