On-Surface Synthesis by Azide–Alkyne Cycloaddition Reactions on Metal Surfaces View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2016

AUTHORS

Oscar Díaz Arado , Harry Mönig , Harald Fuchs

ABSTRACT

On-surface synthesis of covalently bond nanostructures under ultrahigh vacuum conditions has received increased attention in the recent years. This approach allows to study solvent-free chemical reactions and moreover to use well-defined substrates, which act as a catalyst and/or exerting steric effects leading to kinetic and regioselective control of the chemical process at hand. Recently, successful 1,3-dipolar azide–alkyne cycloaddition reactions were performed on metal substrates with complete regioselectivity of a specific product. This chapter presents a summary of these experimental efforts on different metal substrates, while also focusing on a comprehensive understanding of the catalyst prerequisite for on-surface coupling reactions and a quantitative description of steric effects dominating the coupling mechanism and the regioselectivity of the reaction products. Future perspectives for the bottom-up development of functional nanostructures involving on-surface azide–alkyne cycloadditions are discussed. More... »

PAGES

101-114

Book

TITLE

On-Surface Synthesis

ISBN

978-3-319-26598-8
978-3-319-26600-8

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-319-26600-8_5

DOI

http://dx.doi.org/10.1007/978-3-319-26600-8_5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048154281


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of M\u00fcnster", 
          "id": "https://www.grid.ac/institutes/grid.5949.1", 
          "name": [
            "Physikalisches Institut, Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster", 
            "Center for Nanotechnology (CeNTech)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Arado", 
        "givenName": "Oscar D\u00edaz", 
        "id": "sg:person.0673030370.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0673030370.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of M\u00fcnster", 
          "id": "https://www.grid.ac/institutes/grid.5949.1", 
          "name": [
            "Physikalisches Institut, Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster", 
            "Center for Nanotechnology (CeNTech)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "M\u00f6nig", 
        "givenName": "Harry", 
        "id": "sg:person.01305206135.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305206135.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of M\u00fcnster", 
          "id": "https://www.grid.ac/institutes/grid.5949.1", 
          "name": [
            "Physikalisches Institut, Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster", 
            "Center for Nanotechnology (CeNTech)"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fuchs", 
        "givenName": "Harald", 
        "id": "sg:person.0744012231.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0744012231.62"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/elan.200804241", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007180857"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201208597", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008344196"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.1276", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017022818", 
          "https://doi.org/10.1038/nchem.1276"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20010601)40:11<2004::aid-anie2004>3.0.co;2-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027810626"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20010601)40:11<2004::aid-anie2004>3.0.co;2-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027810626"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028820752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1359-6446(03)02933-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032570932"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/asia.201100294", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036510115"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200802229", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043949357"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1165429", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043985293"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja312303a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055854000"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn2033192", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056223814"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol034534r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056243852"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol034534r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056243852"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1211836", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062465532"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016", 
    "datePublishedReg": "2016-01-01", 
    "description": "On-surface synthesis of covalently bond nanostructures under ultrahigh vacuum conditions has received increased attention in the recent years. This approach allows to study solvent-free chemical reactions and moreover to use well-defined substrates, which act as a catalyst and/or exerting steric effects leading to kinetic and regioselective control of the chemical process at hand. Recently, successful 1,3-dipolar azide\u2013alkyne cycloaddition reactions were performed on metal substrates with complete regioselectivity of a specific product. This chapter presents a summary of these experimental efforts on different metal substrates, while also focusing on a comprehensive understanding of the catalyst prerequisite for on-surface coupling reactions and a quantitative description of steric effects dominating the coupling mechanism and the regioselectivity of the reaction products. Future perspectives for the bottom-up development of functional nanostructures involving on-surface azide\u2013alkyne cycloadditions are discussed.", 
    "editor": [
      {
        "familyName": "Gourdon", 
        "givenName": "Andr\u00e9", 
        "type": "Person"
      }
    ], 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/978-3-319-26600-8_5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "978-3-319-26598-8", 
        "978-3-319-26600-8"
      ], 
      "name": "On-Surface Synthesis", 
      "type": "Book"
    }, 
    "name": "On-Surface Synthesis by Azide\u2013Alkyne Cycloaddition Reactions on Metal Surfaces", 
    "pagination": "101-114", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/978-3-319-26600-8_5"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e56625db126947496b6f17b5d55bc83c12822ebc6d19f43f35c4448967bbf4dd"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1048154281"
        ]
      }
    ], 
    "publisher": {
      "location": "Cham", 
      "name": "Springer International Publishing", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/978-3-319-26600-8_5", 
      "https://app.dimensions.ai/details/publication/pub.1048154281"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2019-04-15T18:00", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000082.jsonl", 
    "type": "Chapter", 
    "url": "http://link.springer.com/10.1007/978-3-319-26600-8_5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-26600-8_5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-26600-8_5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-26600-8_5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/978-3-319-26600-8_5'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      23 PREDICATES      40 URIs      20 LITERALS      8 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/978-3-319-26600-8_5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N50dc100c43c649f88be0e48d7396006d
4 schema:citation sg:pub.10.1038/nchem.1276
5 https://doi.org/10.1002/1521-3773(20010601)40:11<2004::aid-anie2004>3.0.co;2-5
6 https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4
7 https://doi.org/10.1002/anie.200802229
8 https://doi.org/10.1002/anie.201208597
9 https://doi.org/10.1002/asia.201100294
10 https://doi.org/10.1002/elan.200804241
11 https://doi.org/10.1016/s1359-6446(03)02933-7
12 https://doi.org/10.1021/ja312303a
13 https://doi.org/10.1021/nn2033192
14 https://doi.org/10.1021/ol034534r
15 https://doi.org/10.1126/science.1165429
16 https://doi.org/10.1126/science.1211836
17 schema:datePublished 2016
18 schema:datePublishedReg 2016-01-01
19 schema:description On-surface synthesis of covalently bond nanostructures under ultrahigh vacuum conditions has received increased attention in the recent years. This approach allows to study solvent-free chemical reactions and moreover to use well-defined substrates, which act as a catalyst and/or exerting steric effects leading to kinetic and regioselective control of the chemical process at hand. Recently, successful 1,3-dipolar azide–alkyne cycloaddition reactions were performed on metal substrates with complete regioselectivity of a specific product. This chapter presents a summary of these experimental efforts on different metal substrates, while also focusing on a comprehensive understanding of the catalyst prerequisite for on-surface coupling reactions and a quantitative description of steric effects dominating the coupling mechanism and the regioselectivity of the reaction products. Future perspectives for the bottom-up development of functional nanostructures involving on-surface azide–alkyne cycloadditions are discussed.
20 schema:editor N50621a7634dc4eed99be80864776406d
21 schema:genre chapter
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf N1d8959c6d2144d46b6f480c59a6885a6
25 schema:name On-Surface Synthesis by Azide–Alkyne Cycloaddition Reactions on Metal Surfaces
26 schema:pagination 101-114
27 schema:productId N3d7f9279411544999d036a8d8492b997
28 N61b75e5cb94047dab3021957bc879ff9
29 Na6fc27b339be495190fece6355183b64
30 schema:publisher N68cdb92a03224b6490e37f3681a3c09d
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048154281
32 https://doi.org/10.1007/978-3-319-26600-8_5
33 schema:sdDatePublished 2019-04-15T18:00
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher N3e5a70590402490da076c322c6d3ce0d
36 schema:url http://link.springer.com/10.1007/978-3-319-26600-8_5
37 sgo:license sg:explorer/license/
38 sgo:sdDataset chapters
39 rdf:type schema:Chapter
40 N1178f0df5486457f84d52b76cdeebd6a rdf:first sg:person.01305206135.83
41 rdf:rest Nbb0975a0a7ea4ff792018c91d7d6cb46
42 N1d8959c6d2144d46b6f480c59a6885a6 schema:isbn 978-3-319-26598-8
43 978-3-319-26600-8
44 schema:name On-Surface Synthesis
45 rdf:type schema:Book
46 N3d7f9279411544999d036a8d8492b997 schema:name dimensions_id
47 schema:value pub.1048154281
48 rdf:type schema:PropertyValue
49 N3e5a70590402490da076c322c6d3ce0d schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 N50621a7634dc4eed99be80864776406d rdf:first Ndbb778e581c147ddaaff875b4e487f0a
52 rdf:rest rdf:nil
53 N50dc100c43c649f88be0e48d7396006d rdf:first sg:person.0673030370.80
54 rdf:rest N1178f0df5486457f84d52b76cdeebd6a
55 N61b75e5cb94047dab3021957bc879ff9 schema:name doi
56 schema:value 10.1007/978-3-319-26600-8_5
57 rdf:type schema:PropertyValue
58 N68cdb92a03224b6490e37f3681a3c09d schema:location Cham
59 schema:name Springer International Publishing
60 rdf:type schema:Organisation
61 Na6fc27b339be495190fece6355183b64 schema:name readcube_id
62 schema:value e56625db126947496b6f17b5d55bc83c12822ebc6d19f43f35c4448967bbf4dd
63 rdf:type schema:PropertyValue
64 Nbb0975a0a7ea4ff792018c91d7d6cb46 rdf:first sg:person.0744012231.62
65 rdf:rest rdf:nil
66 Ndbb778e581c147ddaaff875b4e487f0a schema:familyName Gourdon
67 schema:givenName André
68 rdf:type schema:Person
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
73 schema:name Physical Chemistry (incl. Structural)
74 rdf:type schema:DefinedTerm
75 sg:person.01305206135.83 schema:affiliation https://www.grid.ac/institutes/grid.5949.1
76 schema:familyName Mönig
77 schema:givenName Harry
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01305206135.83
79 rdf:type schema:Person
80 sg:person.0673030370.80 schema:affiliation https://www.grid.ac/institutes/grid.5949.1
81 schema:familyName Arado
82 schema:givenName Oscar Díaz
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0673030370.80
84 rdf:type schema:Person
85 sg:person.0744012231.62 schema:affiliation https://www.grid.ac/institutes/grid.5949.1
86 schema:familyName Fuchs
87 schema:givenName Harald
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0744012231.62
89 rdf:type schema:Person
90 sg:pub.10.1038/nchem.1276 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017022818
91 https://doi.org/10.1038/nchem.1276
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1002/1521-3773(20010601)40:11<2004::aid-anie2004>3.0.co;2-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027810626
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1002/1521-3773(20020715)41:14<2596::aid-anie2596>3.0.co;2-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028820752
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1002/anie.200802229 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043949357
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1002/anie.201208597 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008344196
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1002/asia.201100294 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036510115
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1002/elan.200804241 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007180857
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s1359-6446(03)02933-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032570932
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/ja312303a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055854000
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/nn2033192 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056223814
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/ol034534r schema:sameAs https://app.dimensions.ai/details/publication/pub.1056243852
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1126/science.1165429 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043985293
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1126/science.1211836 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062465532
116 rdf:type schema:CreativeWork
117 https://www.grid.ac/institutes/grid.5949.1 schema:alternateName University of Münster
118 schema:name Center for Nanotechnology (CeNTech)
119 Physikalisches Institut, Westfälische Wilhelms-Universität Münster
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...