Advanced Quantum-Kinetic Model of Energy Exchange in Atmospheric Molecules Mixtures and CO2 Laser-Molecule Interaction View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2021-06-29

AUTHORS

Olga Yu. Khetselius , Alexander V. Glushkov , Sergiy M. Stepanenko , Andrey A. Svinarenko , Vasily V. Buyadzhi

ABSTRACT

We present an advanced quantumQuantum kinetic model-kinetic model for describing nonlinear optical effects due to the interaction of infrared laser radiation with the atmospheric molecules mixtureAtmospheric molecules mixtures (with accounting for the nonlinear radiation transfer and possible chemical conversion mechanisms too). An obvious consequence of the resonant interaction (in particular, absorption) of electromagnetic radiation by atmospheric molecules mixtureAtmospheric molecules mixtures is a quantitative redistribution of molecules over the energy levels of the internal degrees of freedom, which quantitatively changes a gas absorption coefficientGas absorption coefficient. A change in the population levels of the gas mixture causes a violation of the thermodynamic equilibrium between the vibrations of the molecules and their translational motion and causes a nonlinear effect of the kinetic cooling of the atmospheric environment. The calculational data on a temporal dependence of the relative resonant absorption coefficient for rectangular, Gauss and soliton-like laser pulses are presented and analysed. It is clear that the time dependence of the relative resonance absorption coefficient of laser radiation by CO2 molecules differs for different laser pulses. The condition of realization of an atmospheric environment kinetic cooling is obtained and compared with available estimates. More... »

PAGES

207-216

Book

TITLE

Advances in Methods and Applications of Quantum Systems in Chemistry, Physics, and Biology

ISBN

978-3-030-68313-9
978-3-030-68314-6

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-3-030-68314-6_10

DOI

http://dx.doi.org/10.1007/978-3-030-68314-6_10

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1139210323


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