Mössbauer Effect Studies of Oxidic Spinels View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1989

AUTHORS

Robert E. Vandenberghe , Eddy De Grave

ABSTRACT

Since the determination of the crystal structure of the mineral spinel, MgAl2O4, by Bragg,1 and Nishikawa2 in 1915, many metal oxides and mixed metal oxides have been found to possess the same structure,3 and these are usually referred to as spinel compounds or spinels. Such materials, and in particular those containing iron, exhibit suitable combined electrical and magnetic properties and therefore soon became extremely important for many technological applications, such as high-frequency devices, memory cores, and magnetic recording. The rapid expansion of these technologies after World War II was a great stimulus for many researchers to focus their efforts on this kind of ferrite materials. Consequently, the fifties and the early sixties were characterized by intensive investigations of spinel systems with a large variety of compositions. Examples in this respect are the works of Gorter,4,5 followed by that of Blasse,6 reporting structural and magnetic properties of hundreds of new synthetic spinel compounds. The ability of the spinel structure to contain different kinds of cations, which can, moreover, gradually be substituted, made these materials also very suitable for experiments on certain magnetic and structural concepts, new at that time, such as Néel’s ferrimagnetism, ligand field stabilization, and the cooperative Jahn-Teller effect. More... »

PAGES

59-182

References to SciGraph publications

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  • Book

    TITLE

    Mössbauer Spectroscopy Applied to Inorganic Chemistry

    ISBN

    978-1-4899-2291-5
    978-1-4899-2289-2

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-1-4899-2289-2_3

    DOI

    http://dx.doi.org/10.1007/978-1-4899-2289-2_3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1037337228


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