Transport Properties of Single Crystals and Polycrystalline Pressed Samples of (BEDT-TTF)2X Salts and Related Coordination Polymers View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1990

AUTHORS

D. Schweitzer , S. Kahlich , S. Gärtner , E. Gogu , H. Grimm , I. Heinen , T. Klutz , R. Zamboni , H. J. Keller , G. Renner

ABSTRACT

Ten years ago, in 1979, superconductivity was observed for the first time in an organic metal [1]. Today, about 30 different organic metals are known, which become superconducting under pressure or ambient pressure. The organic superconductors with the highest transition temperatures are all radical salts of the donor bis(ethylenedithiolo)-tetrathiafulvalene (BEDT-TTF), namely at ambient pressure (BEDT-TTF)2Cu(NCS)2 (Tc = 10.4 K) [2] and αt-(BEDT-TTF)2I3 (Tc = 8 K) [3] and under isotropic pressure βH - (BEDT-TTF)2I3 (0.5 kbar, Tc = 7.5 K) [4,5]. The latter βH-phase can even become superconducting at 8 K and ambient pressure, after a special pressure-temperature cycling procedure [6], i.e. pressurization up to 1 kbar at room temperature, and release of the helium gas pressure at temperatures below 125 K. Nevertheless, this superconducting state at 8 K in βH-(BEDT-TTF)2I3 is only metastable [6,7], since warming up the crystal above 125 K, and cooling down again under ambient pressure, results only in superconductivity at 1.3 K, the so-called βL - or β-phase. More... »

PAGES

97-114

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-1-4899-2088-1_7

DOI

http://dx.doi.org/10.1007/978-1-4899-2088-1_7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032452572


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