Relation of the Thermochemistry and Phase Diagrams of Condensed Systems View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1975

AUTHORS

Larry Kaufman , Harvey Nesor

ABSTRACT

The relation between the thermochemistry and the phase diagram of a condensed system is an identity. Although this identity was rather well known to the chemists, metallurgists, and ceramists who practiced in the early decades of this century, most practitioners educated after the second world war seem to be unaware of the equivalence. Indeed, the field of phase diagrams is almost exclusively tilled by metallurgists and ceramists, while thermochemical aspects of condensed systems is the exclusive province of chemists. This dichotomy is extremely wasteful since the integrated description of a system permits interrelation of phase diagram and thermochemical data yielding a more complete description of a given system. The description of the magnesium—gallium—aluminum system shown in Table 1 and Figure 1 illustrates the interrelation between thermochemical and phase diagram data and serves to review the whole problem for those who are accustomed to dealing only with the component parts. Table 1 summarizes the free energy of formation of Mg—Ga and Mg—Al compounds at 300°K. These free energies of formation have been calculated from measurements of the thermochemical properties of the Mg—Ga and Mg—Al systems(1,2) using techniques which have been described in detail(3) for combining phase diagram and thermochemical data. More... »

PAGES

179-232

References to SciGraph publications

  • 1972-07. The relative stabilities of Cr23C6/ Cr7C3/ and Cr3C2 and the phase relationships in ternary Cr-Mo-C system in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1972-01. Thermodynamics and phase diagram of the Fe-C system in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1970-07. Activities and phase boundaries in the Cr-Ni system using a solid electrolyte technique in NONE
  • 1972-11. The high temperature thermodynamic properties of Ni-Ti alloys in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1971-09. The formation of Hcp and Bcc phases in austenitic iron alloys in METALLURGICAL TRANSACTIONS A
  • 1972-06. Thermodynamics controlling the proeutectoid ferrite transformations in Fe-C-Mn alloys in METALLURGICAL TRANSACTIONS A
  • 1973-01. The distribution of chromium between ferrite and austenite and the thermodynamics of the α/γ equilibrium in the Fe-Cr and Fe-Mn Systems in METALLURGICAL TRANSACTIONS A
  • 1972-09. High-temperature thermodynamic properties of the chromium carbides determined using the torsion-effusion technique in METALLURGICAL TRANSACTIONS A
  • 1971-08. Solubility of graphite in cobalt and nickel in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1973-04. Experimental and thermodynamic study of the equilibria between ferrite, austenite and intermediate phases in the fe-mo, fe-w, and fe-mo-w systems in METALLURGICAL TRANSACTIONS A
  • 1971-12. Phase relations in concentrated Ta-Hf and Nb-Hf alloys in NONE
  • 1972-01. On the ferrite-austenite equilibrium in the Fe-Cu system in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • Book

    TITLE

    Changes of State

    ISBN

    978-1-4757-1122-6
    978-1-4757-1120-2

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/978-1-4757-1120-2_4

    DOI

    http://dx.doi.org/10.1007/978-1-4757-1120-2_4

    DIMENSIONS

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