Femtosecond Optical Characterization of the Excited State of Rhodobacter Capsulatus DLL View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

1992

AUTHORS

Marten H. Vos , Fabrice Rappaport , Jean-Christophe Lambry , Jacques Breton , Jean-Louis Martin

ABSTRACT

The precursor of photosynthetic electron transfer is the lowest singlet excited state of the pigment complex P*. It is generally accepted that upon population of this state, P* disappears and the radical pair P+HL- is formed in about 3 ps at room temperature (Martin et al.,1986, Woodbury et al.,1985, Holzapfel et al.,1990, Kirmaier and Holten, 1988) and somewhat faster, down to 700 fs, at low temperature (Fleming et al., 1988). However the precise nature of this reaction is subject to debate, especially the role of BL, which is located between P and HL (for a review see Martin and Vos, 1992). It has been proposed that P+BL- is a virtual intermediate in a super-exchange mechanism (Michel-Beyerle et al., 1988, Warshel et al., 1988). Based on the observation of transients faster than P* decay, Zinth and coworkers proposed that P+BL- is a real intermediate, which decays with a faster rate than it is formed (Holzapfel et al., 1989, 1990). More... »

PAGES

237-243

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-1-4615-3050-3_27

DOI

http://dx.doi.org/10.1007/978-1-4615-3050-3_27

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046307661


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