Influence of Differences in Molecular structure on Behavior of and β Relaxation Processes in Diisooctyl Maleate View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2007

AUTHORS

S. Pawlus , M. Paluch , M. Mierzwa , S. Hensel-Bielowka , E. Kaminsha , K. Kaminski , S. J. Rzoska , S. Maślanka

ABSTRACT

Dielectric relaxation measurements have been performed to study effect of the molecular structure on the primary and secondary relaxations in two materials with very similar structure: diisooctyl phthalate (DIOP) and diisooctyl maleate (DIOM). The dielectric spectra were measured over ten decades of frequency and a broad range of temperature. The results show that the temperature dependence of the α-relaxation times cannot be described by a single Vogel–Fulcher–Tammann equation and the temperature dependence of the β-relaxation times in the glassy state obey the Arrhenius law with different activation energies, i.e., EA/k = 4231 K and EA/k = 2917 K for DIOP and DIOM, respectively. Moreover, third relaxation process visible as an excess wing of the high frequency part of the α loss peak was identified in dielectric spectra of DIOM. More... »

PAGES

149-159

Book

TITLE

Soft Matter under Exogenic Impacts

ISBN

978-1-4020-5871-4
978-1-4020-5872-1

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/978-1-4020-5872-1_10

DOI

http://dx.doi.org/10.1007/978-1-4020-5872-1_10

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034370626


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