From Photoinduced Charge Separation to Light-driven Molecular Machines View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2006

AUTHORS

Etienne Baranoff , Francesco Barigelletti , Sylvestre Bonnet , Jean-Paul Collin , Lucia Flamigni , Pierre Mobian , Jean-Pierre Sauvage

ABSTRACT

The photochemical properties of transition metal complexes, such as those of iridium(III) or ruthenium(II),can be exploited in various ways to generate charge-separated (CS) states, in relation to the mimicry ofthe natural photosynthetic reaction centres, or to set multicomponent compounds or assemblies in motion.The first part of the present chapter summarizes the work carried out in our groups (Bologna and Strasbourg)in recent years with iridium(III)-terpy complexes (terpy: 2,2′,6′,6′′-terpyridine).The synthesis of multicomponent iridium(III) complexes in reasonable yields has been achieved and theirphotochemical properties have been investigated. Unexpectedly, the excited state lifetimes of some of thesecompounds are very long at room temperature (several microseconds) in fluid solution, making the Ir(terpy)2 3+fragment an interesting chromophore. Once attached to electron donor (D) groups, dyads of the Ir(terpy)2 3+-Dtype undergo fast photoinduced electron transfer. In addition Ir(terpy)2 3+in the ground state is a relatively good electron acceptor, displaying interesting properties as electronrelay in porphyrinic triads. A triad, consisting of an Ir(terpy)2 3+central core, a Zn porphyrin as the primary donor on one side and a gold(III) porphyrin as theterminal acceptor on the other side, leads to a relatively long-lived CS state (close to the microsecond).The other section of the present chapter deals with light-driven molecular machines built around Ru(bpy)3 2+derivatives, including catenanes and rotaxanes. In order to set the system in motion, a dissociativeligand field (LF) state is generated from the light-absorbing metal-to-ligand charge transfer (MLCT) state,originating in the expulsion of a given ligand in a perfectly controlled fashion. This step israpidly followed by coordination of another ligand to afford a kinetically stable new complex. Theprocess can be inverted by thermal energy, so as to regenerate the starting state of the system. More... »

PAGES

41-78

References to SciGraph publications

Book

TITLE

Photofunctional Transition Metal Complexes

ISBN

978-3-540-36809-0
978-3-540-36810-6

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/430_037

DOI

http://dx.doi.org/10.1007/430_037

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006342426


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, UMR 7513 du CNRS, Institut Le Bel, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67000\u00a0Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Baranoff", 
        "givenName": "Etienne", 
        "id": "sg:person.01156476226.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01156476226.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis and Photoreactivity", 
          "id": "https://www.grid.ac/institutes/grid.494653.9", 
          "name": [
            "Istituto ISOF-CNR, Via P. Gobetti 101, 40129\u00a0Bologna, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Barigelletti", 
        "givenName": "Francesco", 
        "id": "sg:person.01155567427.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01155567427.62"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, UMR 7513 du CNRS, Institut Le Bel, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67000\u00a0Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bonnet", 
        "givenName": "Sylvestre", 
        "id": "sg:person.01162374423.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01162374423.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, UMR 7513 du CNRS, Institut Le Bel, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67000\u00a0Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Collin", 
        "givenName": "Jean-Paul", 
        "id": "sg:person.01366767603.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01366767603.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Synthesis and Photoreactivity", 
          "id": "https://www.grid.ac/institutes/grid.494653.9", 
          "name": [
            "Istituto ISOF-CNR, Via P. Gobetti 101, 40129\u00a0Bologna, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Flamigni", 
        "givenName": "Lucia", 
        "id": "sg:person.01347200200.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01347200200.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, UMR 7513 du CNRS, Institut Le Bel, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67000\u00a0Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mobian", 
        "givenName": "Pierre", 
        "id": "sg:person.01120447043.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01120447043.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire de Chimie Organo-Min\u00e9rale, UMR 7513 du CNRS, Institut Le Bel, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67000\u00a0Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sauvage", 
        "givenName": "Jean-Pierre", 
        "id": "sg:person.01025725303.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025725303.67"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/b407291j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000973541"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b007192g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001045760"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1521-3773(20000403)39:7<1292::aid-anie1292>3.0.co;2-v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003282110"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jcc.540160702", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005411416"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b000704h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005873317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol049082c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006667569"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol049082c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006667569"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2004.08.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008995315"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-8545(94)80030-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010334039"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ccr.2004.07.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010432946"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic035137f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013799190"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic035137f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013799190"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200400284", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016739355"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b207502d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017345960"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3765(20001002)6:19<3558::aid-chem3558>3.0.co;2-m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021619645"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.199313011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024797398"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic058006i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025388185"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic058006i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025388185"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.19880710525", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025658329"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200460568", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025899370"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200352522", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026428363"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/43646", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026557500", 
          "https://doi.org/10.1038/43646"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/43646", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026557500", 
          "https://doi.org/10.1038/43646"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b316486c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028555296"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-8545(90)80098-e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030912596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.199311113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031490708"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja003693s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032257960"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja003693s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032257960"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja012499i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032671688"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja012499i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032671688"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200250613", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035148131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic980847k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037471372"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic980847k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037471372"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-8545(88)80032-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039134373"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.200400544", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042533450"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.200400544", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042533450"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja036782o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042859749"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja036782o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042859749"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja034732d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043349808"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja034732d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043349808"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic048247a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043375827"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic048247a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043375827"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200304716", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046070657"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-8545(98)90005-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047282558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-8545(98)90005-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047282558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200304334", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047485712"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja034994f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050563315"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja034994f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050563315"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp963773b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050747386"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp963773b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050747386"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic050904r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051885304"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic050904r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051885304"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.200390345", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052602805"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1521-3765(19980904)4:9<1744::aid-chem1744>3.0.co;2-a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052845228"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0009-2614(81)85312-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052906464"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00028a006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053930543"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac980234p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055075270"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac980234p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055075270"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar9701068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055152242"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar9701068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055152242"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00004a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055537574"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00022a026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055538463"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00046a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055539661"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00075a048", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055541093"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00178a028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055546079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00303a034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055551278"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic010416t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553554"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic010416t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553554"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic011014o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553978"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic011014o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553978"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0346984", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055555939"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0346984", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055555939"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0351038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055556194"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0351038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055556194"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0491736", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557120"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0491736", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557120"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic050311g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557779"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic050311g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557779"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0505605", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0505605", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055557915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic051296i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055558359"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic051296i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055558359"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50190a016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055578252"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic971121b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055588139"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic971121b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055588139"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100407a046", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055669454"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00022a062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055699834"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00065a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055703640"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00077a024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055704829"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00142a012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055709260"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00242a050", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055717044"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00382a012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055727918"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00538a026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055740357"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00778a054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055747079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00813a064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055750015"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00846a058", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055752509"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0209215", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055826177"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0209215", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055826177"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja021413y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055827346"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja021413y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055827346"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0280729", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055831576"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0280729", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055831576"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja055243b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055840048"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja055243b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055840048"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja963955j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055866431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja963955j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055866431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja971438a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867683"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja971438a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867683"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja9720826", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867986"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja9720826", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055867986"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja9833669", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055870870"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja984051w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055871180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp025509q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056050491"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp025509q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056050491"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp953606w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056121129"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp953606w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056121129"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9716389", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056125125"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp9716389", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056125125"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol0300367", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056243521"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ol0300367", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056243521"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1306639", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057692770"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006", 
    "datePublishedReg": "2006-01-01", 
    "description": "The photochemical properties of transition metal complexes, such as those of iridium(III) or ruthenium(II),can be exploited in various ways to generate charge-separated (CS) states, in relation to the mimicry ofthe natural photosynthetic reaction centres, or to set multicomponent compounds or assemblies in motion.The first part of the present chapter summarizes the work carried out in our groups (Bologna and Strasbourg)in recent years with iridium(III)-terpy complexes (terpy: 2,2\u2032,6\u2032,6\u2032\u2032-terpyridine).The synthesis of multicomponent iridium(III) complexes in reasonable yields has been achieved and theirphotochemical properties have been investigated. Unexpectedly, the excited state lifetimes of some of thesecompounds are very long at room temperature (several microseconds) in fluid solution, making the Ir(terpy)2 3+fragment an interesting chromophore. Once attached to electron donor (D) groups, dyads of the Ir(terpy)2 3+-Dtype undergo fast photoinduced electron transfer. In addition Ir(terpy)2 3+in the ground state is a\u00a0relatively good electron acceptor, displaying interesting properties as electronrelay in porphyrinic triads. A\u00a0triad, consisting of an Ir(terpy)2 3+central core, a\u00a0Zn porphyrin as the primary donor on one side and a\u00a0gold(III) porphyrin as theterminal acceptor on the other side, leads to a\u00a0relatively long-lived CS state (close to the microsecond).The other section of the present chapter deals with light-driven molecular machines built around Ru(bpy)3 2+derivatives, including catenanes and rotaxanes. In order to set the system in motion, a\u00a0dissociativeligand field (LF) state is generated from the light-absorbing metal-to-ligand charge transfer (MLCT) state,originating in the expulsion of a\u00a0given ligand in a\u00a0perfectly controlled fashion. This step israpidly followed by coordination of another ligand to afford a\u00a0kinetically stable new complex. Theprocess can be inverted by thermal energy, so as to regenerate the starting state of the system.", 
    "editor": [
      {
        "familyName": "Yam", 
        "givenName": "Vivian W. W.", 
        "type": "Person"
      }
    ], 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/430_037", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "978-3-540-36809-0", 
        "978-3-540-36810-6"
      ], 
      "name": "Photofunctional Transition Metal Complexes", 
      "type": "Book"
    }, 
    "name": "From Photoinduced Charge Separation to Light-driven Molecular Machines", 
    "pagination": "41-78", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/430_037"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1e35d1f4546fc7b1e94a92ec880f5a4c26ff031962a57f0edb147059a480991e"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006342426"
        ]
      }
    ], 
    "publisher": {
      "location": "Berlin, Heidelberg", 
      "name": "Springer Berlin Heidelberg", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/430_037", 
      "https://app.dimensions.ai/details/publication/pub.1006342426"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2019-04-15T10:31", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000247.jsonl", 
    "type": "Chapter", 
    "url": "http://link.springer.com/10.1007/430_037"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/430_037'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/430_037'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/430_037'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/430_037'


 

This table displays all metadata directly associated to this object as RDF triples.

363 TRIPLES      23 PREDICATES      111 URIs      20 LITERALS      8 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/430_037 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd96aa9c4d2c7420d9808eef5194390fa
4 schema:citation sg:pub.10.1038/43646
5 https://doi.org/10.1002/(sici)1521-3765(19980904)4:9<1744::aid-chem1744>3.0.co;2-a
6 https://doi.org/10.1002/(sici)1521-3773(20000403)39:7<1292::aid-anie1292>3.0.co;2-v
7 https://doi.org/10.1002/1521-3765(20001002)6:19<3558::aid-chem3558>3.0.co;2-m
8 https://doi.org/10.1002/adfm.200304334
9 https://doi.org/10.1002/adma.200400284
10 https://doi.org/10.1002/anie.199311113
11 https://doi.org/10.1002/anie.199313011
12 https://doi.org/10.1002/anie.200250613
13 https://doi.org/10.1002/anie.200352522
14 https://doi.org/10.1002/anie.200460568
15 https://doi.org/10.1002/chem.200304716
16 https://doi.org/10.1002/hlca.19880710525
17 https://doi.org/10.1002/hlca.200390345
18 https://doi.org/10.1002/jcc.540160702
19 https://doi.org/10.1002/macp.200400544
20 https://doi.org/10.1016/0009-2614(81)85312-2
21 https://doi.org/10.1016/0010-8545(88)80032-8
22 https://doi.org/10.1016/0010-8545(90)80098-e
23 https://doi.org/10.1016/0010-8545(94)80030-8
24 https://doi.org/10.1016/j.ccr.2004.07.005
25 https://doi.org/10.1016/j.poly.2004.08.009
26 https://doi.org/10.1016/s0010-8545(98)90005-4
27 https://doi.org/10.1021/ac980234p
28 https://doi.org/10.1021/ar9701068
29 https://doi.org/10.1021/cr00028a006
30 https://doi.org/10.1021/ic00004a013
31 https://doi.org/10.1021/ic00022a026
32 https://doi.org/10.1021/ic00046a023
33 https://doi.org/10.1021/ic00075a048
34 https://doi.org/10.1021/ic00178a028
35 https://doi.org/10.1021/ic00303a034
36 https://doi.org/10.1021/ic010416t
37 https://doi.org/10.1021/ic011014o
38 https://doi.org/10.1021/ic0346984
39 https://doi.org/10.1021/ic0351038
40 https://doi.org/10.1021/ic035137f
41 https://doi.org/10.1021/ic048247a
42 https://doi.org/10.1021/ic0491736
43 https://doi.org/10.1021/ic050311g
44 https://doi.org/10.1021/ic0505605
45 https://doi.org/10.1021/ic050904r
46 https://doi.org/10.1021/ic051296i
47 https://doi.org/10.1021/ic058006i
48 https://doi.org/10.1021/ic50190a016
49 https://doi.org/10.1021/ic971121b
50 https://doi.org/10.1021/ic980847k
51 https://doi.org/10.1021/j100407a046
52 https://doi.org/10.1021/ja00022a062
53 https://doi.org/10.1021/ja00065a023
54 https://doi.org/10.1021/ja00077a024
55 https://doi.org/10.1021/ja00142a012
56 https://doi.org/10.1021/ja00242a050
57 https://doi.org/10.1021/ja003693s
58 https://doi.org/10.1021/ja00382a012
59 https://doi.org/10.1021/ja00538a026
60 https://doi.org/10.1021/ja00778a054
61 https://doi.org/10.1021/ja00813a064
62 https://doi.org/10.1021/ja00846a058
63 https://doi.org/10.1021/ja012499i
64 https://doi.org/10.1021/ja0209215
65 https://doi.org/10.1021/ja021413y
66 https://doi.org/10.1021/ja0280729
67 https://doi.org/10.1021/ja034732d
68 https://doi.org/10.1021/ja034994f
69 https://doi.org/10.1021/ja036782o
70 https://doi.org/10.1021/ja055243b
71 https://doi.org/10.1021/ja963955j
72 https://doi.org/10.1021/ja971438a
73 https://doi.org/10.1021/ja9720826
74 https://doi.org/10.1021/ja9833669
75 https://doi.org/10.1021/ja984051w
76 https://doi.org/10.1021/jp025509q
77 https://doi.org/10.1021/jp953606w
78 https://doi.org/10.1021/jp963773b
79 https://doi.org/10.1021/jp9716389
80 https://doi.org/10.1021/ol0300367
81 https://doi.org/10.1021/ol049082c
82 https://doi.org/10.1039/b000704h
83 https://doi.org/10.1039/b007192g
84 https://doi.org/10.1039/b207502d
85 https://doi.org/10.1039/b316486c
86 https://doi.org/10.1039/b407291j
87 https://doi.org/10.1063/1.1306639
88 schema:datePublished 2006
89 schema:datePublishedReg 2006-01-01
90 schema:description The photochemical properties of transition metal complexes, such as those of iridium(III) or ruthenium(II),can be exploited in various ways to generate charge-separated (CS) states, in relation to the mimicry ofthe natural photosynthetic reaction centres, or to set multicomponent compounds or assemblies in motion.The first part of the present chapter summarizes the work carried out in our groups (Bologna and Strasbourg)in recent years with iridium(III)-terpy complexes (terpy: 2,2′,6′,6′′-terpyridine).The synthesis of multicomponent iridium(III) complexes in reasonable yields has been achieved and theirphotochemical properties have been investigated. Unexpectedly, the excited state lifetimes of some of thesecompounds are very long at room temperature (several microseconds) in fluid solution, making the Ir(terpy)2 3+fragment an interesting chromophore. Once attached to electron donor (D) groups, dyads of the Ir(terpy)2 3+-Dtype undergo fast photoinduced electron transfer. In addition Ir(terpy)2 3+in the ground state is a relatively good electron acceptor, displaying interesting properties as electronrelay in porphyrinic triads. A triad, consisting of an Ir(terpy)2 3+central core, a Zn porphyrin as the primary donor on one side and a gold(III) porphyrin as theterminal acceptor on the other side, leads to a relatively long-lived CS state (close to the microsecond).The other section of the present chapter deals with light-driven molecular machines built around Ru(bpy)3 2+derivatives, including catenanes and rotaxanes. In order to set the system in motion, a dissociativeligand field (LF) state is generated from the light-absorbing metal-to-ligand charge transfer (MLCT) state,originating in the expulsion of a given ligand in a perfectly controlled fashion. This step israpidly followed by coordination of another ligand to afford a kinetically stable new complex. Theprocess can be inverted by thermal energy, so as to regenerate the starting state of the system.
91 schema:editor Nf42b33205aaa41b287e3ad85e97c3f3f
92 schema:genre chapter
93 schema:inLanguage en
94 schema:isAccessibleForFree false
95 schema:isPartOf N031711197ffb47efbd9de4512e2b74cc
96 schema:name From Photoinduced Charge Separation to Light-driven Molecular Machines
97 schema:pagination 41-78
98 schema:productId N11ff57517d854bb3ba2ce4b57299cd23
99 N266771564391482fb13e370153221aba
100 Nd8eb7225b973439f8235a0784b3e8505
101 schema:publisher Na4300c2f55ff497e83cf57312391026c
102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006342426
103 https://doi.org/10.1007/430_037
104 schema:sdDatePublished 2019-04-15T10:31
105 schema:sdLicense https://scigraph.springernature.com/explorer/license/
106 schema:sdPublisher N8cc3c607266a4bd3b5fbf969c71de203
107 schema:url http://link.springer.com/10.1007/430_037
108 sgo:license sg:explorer/license/
109 sgo:sdDataset chapters
110 rdf:type schema:Chapter
111 N031711197ffb47efbd9de4512e2b74cc schema:isbn 978-3-540-36809-0
112 978-3-540-36810-6
113 schema:name Photofunctional Transition Metal Complexes
114 rdf:type schema:Book
115 N11ff57517d854bb3ba2ce4b57299cd23 schema:name doi
116 schema:value 10.1007/430_037
117 rdf:type schema:PropertyValue
118 N20bde623acf94dc39b34eb6ab82ed866 rdf:first sg:person.01025725303.67
119 rdf:rest rdf:nil
120 N266771564391482fb13e370153221aba schema:name dimensions_id
121 schema:value pub.1006342426
122 rdf:type schema:PropertyValue
123 N8bfe87ec930740b1a88aea7c7ff6f8c8 rdf:first sg:person.01347200200.12
124 rdf:rest Nab16e7d50cb64bf09afd4ed60ab297a2
125 N8cc3c607266a4bd3b5fbf969c71de203 schema:name Springer Nature - SN SciGraph project
126 rdf:type schema:Organization
127 Na4300c2f55ff497e83cf57312391026c schema:location Berlin, Heidelberg
128 schema:name Springer Berlin Heidelberg
129 rdf:type schema:Organisation
130 Nab16e7d50cb64bf09afd4ed60ab297a2 rdf:first sg:person.01120447043.37
131 rdf:rest N20bde623acf94dc39b34eb6ab82ed866
132 Nbd57b4885f5546fc86ca685feefd6a29 rdf:first sg:person.01162374423.79
133 rdf:rest Ne528228700d04e13ae395ec88d1268f4
134 Nd85673c075b8463d9100dbd2311902e5 schema:familyName Yam
135 schema:givenName Vivian W. W.
136 rdf:type schema:Person
137 Nd8eb7225b973439f8235a0784b3e8505 schema:name readcube_id
138 schema:value 1e35d1f4546fc7b1e94a92ec880f5a4c26ff031962a57f0edb147059a480991e
139 rdf:type schema:PropertyValue
140 Nd96aa9c4d2c7420d9808eef5194390fa rdf:first sg:person.01156476226.07
141 rdf:rest Nffe98d43f8b74c4fbb6bbca4cc4ef93b
142 Ne528228700d04e13ae395ec88d1268f4 rdf:first sg:person.01366767603.47
143 rdf:rest N8bfe87ec930740b1a88aea7c7ff6f8c8
144 Nf42b33205aaa41b287e3ad85e97c3f3f rdf:first Nd85673c075b8463d9100dbd2311902e5
145 rdf:rest rdf:nil
146 Nffe98d43f8b74c4fbb6bbca4cc4ef93b rdf:first sg:person.01155567427.62
147 rdf:rest Nbd57b4885f5546fc86ca685feefd6a29
148 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
149 schema:name Chemical Sciences
150 rdf:type schema:DefinedTerm
151 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
152 schema:name Physical Chemistry (incl. Structural)
153 rdf:type schema:DefinedTerm
154 sg:person.01025725303.67 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
155 schema:familyName Sauvage
156 schema:givenName Jean-Pierre
157 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025725303.67
158 rdf:type schema:Person
159 sg:person.01120447043.37 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
160 schema:familyName Mobian
161 schema:givenName Pierre
162 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01120447043.37
163 rdf:type schema:Person
164 sg:person.01155567427.62 schema:affiliation https://www.grid.ac/institutes/grid.494653.9
165 schema:familyName Barigelletti
166 schema:givenName Francesco
167 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01155567427.62
168 rdf:type schema:Person
169 sg:person.01156476226.07 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
170 schema:familyName Baranoff
171 schema:givenName Etienne
172 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01156476226.07
173 rdf:type schema:Person
174 sg:person.01162374423.79 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
175 schema:familyName Bonnet
176 schema:givenName Sylvestre
177 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01162374423.79
178 rdf:type schema:Person
179 sg:person.01347200200.12 schema:affiliation https://www.grid.ac/institutes/grid.494653.9
180 schema:familyName Flamigni
181 schema:givenName Lucia
182 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01347200200.12
183 rdf:type schema:Person
184 sg:person.01366767603.47 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
185 schema:familyName Collin
186 schema:givenName Jean-Paul
187 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01366767603.47
188 rdf:type schema:Person
189 sg:pub.10.1038/43646 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026557500
190 https://doi.org/10.1038/43646
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1002/(sici)1521-3765(19980904)4:9<1744::aid-chem1744>3.0.co;2-a schema:sameAs https://app.dimensions.ai/details/publication/pub.1052845228
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1002/(sici)1521-3773(20000403)39:7<1292::aid-anie1292>3.0.co;2-v schema:sameAs https://app.dimensions.ai/details/publication/pub.1003282110
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1002/1521-3765(20001002)6:19<3558::aid-chem3558>3.0.co;2-m schema:sameAs https://app.dimensions.ai/details/publication/pub.1021619645
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1002/adfm.200304334 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047485712
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1002/adma.200400284 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016739355
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1002/anie.199311113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031490708
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1002/anie.199313011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024797398
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1002/anie.200250613 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035148131
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1002/anie.200352522 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026428363
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1002/anie.200460568 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025899370
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1002/chem.200304716 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046070657
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1002/hlca.19880710525 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025658329
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1002/hlca.200390345 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052602805
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1002/jcc.540160702 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005411416
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1002/macp.200400544 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042533450
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1016/0009-2614(81)85312-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052906464
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1016/0010-8545(88)80032-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039134373
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1016/0010-8545(90)80098-e schema:sameAs https://app.dimensions.ai/details/publication/pub.1030912596
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1016/0010-8545(94)80030-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010334039
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1016/j.ccr.2004.07.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010432946
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1016/j.poly.2004.08.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008995315
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1016/s0010-8545(98)90005-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047282558
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1021/ac980234p schema:sameAs https://app.dimensions.ai/details/publication/pub.1055075270
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1021/ar9701068 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055152242
239 rdf:type schema:CreativeWork
240 https://doi.org/10.1021/cr00028a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053930543
241 rdf:type schema:CreativeWork
242 https://doi.org/10.1021/ic00004a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055537574
243 rdf:type schema:CreativeWork
244 https://doi.org/10.1021/ic00022a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055538463
245 rdf:type schema:CreativeWork
246 https://doi.org/10.1021/ic00046a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055539661
247 rdf:type schema:CreativeWork
248 https://doi.org/10.1021/ic00075a048 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055541093
249 rdf:type schema:CreativeWork
250 https://doi.org/10.1021/ic00178a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055546079
251 rdf:type schema:CreativeWork
252 https://doi.org/10.1021/ic00303a034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055551278
253 rdf:type schema:CreativeWork
254 https://doi.org/10.1021/ic010416t schema:sameAs https://app.dimensions.ai/details/publication/pub.1055553554
255 rdf:type schema:CreativeWork
256 https://doi.org/10.1021/ic011014o schema:sameAs https://app.dimensions.ai/details/publication/pub.1055553978
257 rdf:type schema:CreativeWork
258 https://doi.org/10.1021/ic0346984 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055555939
259 rdf:type schema:CreativeWork
260 https://doi.org/10.1021/ic0351038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055556194
261 rdf:type schema:CreativeWork
262 https://doi.org/10.1021/ic035137f schema:sameAs https://app.dimensions.ai/details/publication/pub.1013799190
263 rdf:type schema:CreativeWork
264 https://doi.org/10.1021/ic048247a schema:sameAs https://app.dimensions.ai/details/publication/pub.1043375827
265 rdf:type schema:CreativeWork
266 https://doi.org/10.1021/ic0491736 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055557120
267 rdf:type schema:CreativeWork
268 https://doi.org/10.1021/ic050311g schema:sameAs https://app.dimensions.ai/details/publication/pub.1055557779
269 rdf:type schema:CreativeWork
270 https://doi.org/10.1021/ic0505605 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055557915
271 rdf:type schema:CreativeWork
272 https://doi.org/10.1021/ic050904r schema:sameAs https://app.dimensions.ai/details/publication/pub.1051885304
273 rdf:type schema:CreativeWork
274 https://doi.org/10.1021/ic051296i schema:sameAs https://app.dimensions.ai/details/publication/pub.1055558359
275 rdf:type schema:CreativeWork
276 https://doi.org/10.1021/ic058006i schema:sameAs https://app.dimensions.ai/details/publication/pub.1025388185
277 rdf:type schema:CreativeWork
278 https://doi.org/10.1021/ic50190a016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055578252
279 rdf:type schema:CreativeWork
280 https://doi.org/10.1021/ic971121b schema:sameAs https://app.dimensions.ai/details/publication/pub.1055588139
281 rdf:type schema:CreativeWork
282 https://doi.org/10.1021/ic980847k schema:sameAs https://app.dimensions.ai/details/publication/pub.1037471372
283 rdf:type schema:CreativeWork
284 https://doi.org/10.1021/j100407a046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055669454
285 rdf:type schema:CreativeWork
286 https://doi.org/10.1021/ja00022a062 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055699834
287 rdf:type schema:CreativeWork
288 https://doi.org/10.1021/ja00065a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055703640
289 rdf:type schema:CreativeWork
290 https://doi.org/10.1021/ja00077a024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055704829
291 rdf:type schema:CreativeWork
292 https://doi.org/10.1021/ja00142a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055709260
293 rdf:type schema:CreativeWork
294 https://doi.org/10.1021/ja00242a050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055717044
295 rdf:type schema:CreativeWork
296 https://doi.org/10.1021/ja003693s schema:sameAs https://app.dimensions.ai/details/publication/pub.1032257960
297 rdf:type schema:CreativeWork
298 https://doi.org/10.1021/ja00382a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055727918
299 rdf:type schema:CreativeWork
300 https://doi.org/10.1021/ja00538a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055740357
301 rdf:type schema:CreativeWork
302 https://doi.org/10.1021/ja00778a054 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055747079
303 rdf:type schema:CreativeWork
304 https://doi.org/10.1021/ja00813a064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055750015
305 rdf:type schema:CreativeWork
306 https://doi.org/10.1021/ja00846a058 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055752509
307 rdf:type schema:CreativeWork
308 https://doi.org/10.1021/ja012499i schema:sameAs https://app.dimensions.ai/details/publication/pub.1032671688
309 rdf:type schema:CreativeWork
310 https://doi.org/10.1021/ja0209215 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055826177
311 rdf:type schema:CreativeWork
312 https://doi.org/10.1021/ja021413y schema:sameAs https://app.dimensions.ai/details/publication/pub.1055827346
313 rdf:type schema:CreativeWork
314 https://doi.org/10.1021/ja0280729 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055831576
315 rdf:type schema:CreativeWork
316 https://doi.org/10.1021/ja034732d schema:sameAs https://app.dimensions.ai/details/publication/pub.1043349808
317 rdf:type schema:CreativeWork
318 https://doi.org/10.1021/ja034994f schema:sameAs https://app.dimensions.ai/details/publication/pub.1050563315
319 rdf:type schema:CreativeWork
320 https://doi.org/10.1021/ja036782o schema:sameAs https://app.dimensions.ai/details/publication/pub.1042859749
321 rdf:type schema:CreativeWork
322 https://doi.org/10.1021/ja055243b schema:sameAs https://app.dimensions.ai/details/publication/pub.1055840048
323 rdf:type schema:CreativeWork
324 https://doi.org/10.1021/ja963955j schema:sameAs https://app.dimensions.ai/details/publication/pub.1055866431
325 rdf:type schema:CreativeWork
326 https://doi.org/10.1021/ja971438a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055867683
327 rdf:type schema:CreativeWork
328 https://doi.org/10.1021/ja9720826 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055867986
329 rdf:type schema:CreativeWork
330 https://doi.org/10.1021/ja9833669 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055870870
331 rdf:type schema:CreativeWork
332 https://doi.org/10.1021/ja984051w schema:sameAs https://app.dimensions.ai/details/publication/pub.1055871180
333 rdf:type schema:CreativeWork
334 https://doi.org/10.1021/jp025509q schema:sameAs https://app.dimensions.ai/details/publication/pub.1056050491
335 rdf:type schema:CreativeWork
336 https://doi.org/10.1021/jp953606w schema:sameAs https://app.dimensions.ai/details/publication/pub.1056121129
337 rdf:type schema:CreativeWork
338 https://doi.org/10.1021/jp963773b schema:sameAs https://app.dimensions.ai/details/publication/pub.1050747386
339 rdf:type schema:CreativeWork
340 https://doi.org/10.1021/jp9716389 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056125125
341 rdf:type schema:CreativeWork
342 https://doi.org/10.1021/ol0300367 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056243521
343 rdf:type schema:CreativeWork
344 https://doi.org/10.1021/ol049082c schema:sameAs https://app.dimensions.ai/details/publication/pub.1006667569
345 rdf:type schema:CreativeWork
346 https://doi.org/10.1039/b000704h schema:sameAs https://app.dimensions.ai/details/publication/pub.1005873317
347 rdf:type schema:CreativeWork
348 https://doi.org/10.1039/b007192g schema:sameAs https://app.dimensions.ai/details/publication/pub.1001045760
349 rdf:type schema:CreativeWork
350 https://doi.org/10.1039/b207502d schema:sameAs https://app.dimensions.ai/details/publication/pub.1017345960
351 rdf:type schema:CreativeWork
352 https://doi.org/10.1039/b316486c schema:sameAs https://app.dimensions.ai/details/publication/pub.1028555296
353 rdf:type schema:CreativeWork
354 https://doi.org/10.1039/b407291j schema:sameAs https://app.dimensions.ai/details/publication/pub.1000973541
355 rdf:type schema:CreativeWork
356 https://doi.org/10.1063/1.1306639 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057692770
357 rdf:type schema:CreativeWork
358 https://www.grid.ac/institutes/grid.11843.3f schema:alternateName University of Strasbourg
359 schema:name Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, 67000 Strasbourg Cedex, France
360 rdf:type schema:Organization
361 https://www.grid.ac/institutes/grid.494653.9 schema:alternateName Institute of Organic Synthesis and Photoreactivity
362 schema:name Istituto ISOF-CNR, Via P. Gobetti 101, 40129 Bologna, Italy
363 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...