Recent Advances in the Study of Synthetic Polyampholytes in Solutions View Full Text


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Chapter Info

DATE

1999-05-27

AUTHORS

Sarkyt E. Kudaibergenov

ABSTRACT

This article reviews the theoretical and experimental material accumulated in recent years on water-soluble and water-swelling polyampholytes of integral and pendant types. The theory of polyampholytes in comparison with experimental results, acid-base equilibrium, hydrodynamic, conformational, and the molecular and colloidal properties of amphoteric copolymers are considered. The responsibility of Coulomb forces, hydrogen bonds and hydrophobic interactions in the formation of compact structures is shown. Basic attention is paid to the specific structure and behaviour of polyampholytes at or near the isoelectric point (IEP), in particular to the “forcing out” phenomenon found at the IEP. The ability of polyampholytes to associate with various low- and high-molecular-weight substances as well as to be absorbed on dispersed particles is discussed. An attempt to show the closeness of structural organization or molecular recognition of synthetic polyampholytes to natural ones is undertaken. More... »

PAGES

115-197

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  • Book

    TITLE

    Polymer Latexes - Epoxide Resins - Polyampholytes

    ISBN

    978-3-540-64911-3

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/3-540-68384-4_3

    DOI

    http://dx.doi.org/10.1007/3-540-68384-4_3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1051641013


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