Speciation of Colloid-borne Uranium by EXAFS and ATR-FTIR spectroscopy View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2006

AUTHORS

Kai-Uwe Ulrich , André Rossberg , Andreas C. Scheinost , Harald Foerstendorf , Harald Zänker , Ulf Jenk

ABSTRACT

De-acidification of acid mine waters transfers dissolved uranium into a colloidal form. Spectroscopic studies on colloid-borne uranium obtained by simulation of mine flooding in the laboratory showed that matrix ions such as sulfate and silicate are not involved in inner-sphere surface sorption complexes of UO2 2+ on ferrihydrite. At ambient air atmosphere, the data suggest the formation of ternary U(VI) carbonato surface complexes with either monodentate or bidentate coordination of carbonate and uranyl even at moderately acidic conditions. A revised model is proposed for UO2 2+ sorption on ferrihydrite in the absence of carbonate. More... »

PAGES

137-147

References to SciGraph publications

Book

TITLE

Uranium in the Environment

ISBN

3-540-28363-3

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/3-540-28367-6_13

DOI

http://dx.doi.org/10.1007/3-540-28367-6_13

DIMENSIONS

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