Two-Photon Absorbing Materials and Two-Photon-Induced Chemistry View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2008-05-23

AUTHORS

Mariacristina Rumi , Stephen Barlow , Jing Wang , Joseph W. Perry , Seth R. Marder

ABSTRACT

Two-photon absorption, the process by which an excited molecule or material is produced by the simultaneousabsorption of two photons, has been studied extensively in recent years, from both fundamental and applicationpoints of view. On one side, the field has been expanded with the measurement of two-photon absorptionspectra and cross sections for a wide range of conjugated molecules. In this contribution, we willreview the two-photon properties of some of these classes of materials, and we will discuss structure/propertyrelationships that have been developed from these investigations. On the other side, two-photon absorptionhas been exploited as a means to activate a variety of chemical and physical processes with sub-diffraction–limitedresolution, because three-dimensional spatial confinement of the excitation volume in a material irradiatedby a tightly focused laser beam can be achieved via two-photon or, more generally, multi-photon absorptionprocesses. This characteristic has led to applications in a number of technological fields, such asmicrofabrication and laser scanning fluorescence microscopy. Here, we will survey material systems thathave been developed to activate radical or cationic polymerization reactions, deprotection of functionalgroups, and singlet oxygen generation via two-photon excitation of one of the components in the system. More... »

PAGES

1-95

Book

TITLE

Photoresponsive Polymers I

ISBN

978-3-540-69448-9
978-3-540-69450-2

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/12_2008_133

DOI

http://dx.doi.org/10.1007/12_2008_133

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033643052


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