Halonium Ions as Halogen Bond Donors in the Solid State [XL2]Y Complexes View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2015

AUTHORS

Kari Rissanen , Matti Haukka

ABSTRACT

The utilization of halogen bonding interactions is one of the most rapidly developing areas of supramolecular chemistry. While the other weak non-covalent interactions and their influence on the structure and chemistry of various molecules, complexes, and materials have been investigated extensively, the understanding, utilizations, and true nature of halogen bonding are still relatively unexplored. Thus its final impact in chemistry in general and in materials science has not yet been fully established. Because of the polarized nature of a Z-X bond (Z=electron-withdrawing atom or moiety and X=halogen atom), such a moiety can act as halogen bond donor when the halogen is polarized enough by the atom/moiety Z. The most studied and utilized halogen bond donor molecules are the perfluorohalocarbons, where Z is a perfluorinated aryl or alkyl moiety and X is either iodine or bromine. Complementing the contemporary halogen bonding research, this chapter reviews the solid state structural chemistry of the most extremely polarized halogen atoms, viz. halonium ions, X+, and discussed them as halogen bond donors in the solid state [XL2]Y complexes (X=halonium ion, Y=any anion). More... »

PAGES

77-90

References to SciGraph publications

  • 2007-02. An overview of halogen bonding in JOURNAL OF MOLECULAR MODELING
  • 2012-01. Transmembrane anion transport mediated by halogen-bond donors in NATURE COMMUNICATIONS
  • Book

    TITLE

    Halogen Bonding II

    ISBN

    978-3-319-15731-3
    978-3-319-15732-0

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/128_2014_587

    DOI

    http://dx.doi.org/10.1007/128_2014_587

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1006098734

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/25863815


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