Magnetic Defects In Pristine And Hydrogenterminated Nanodiamonds View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2006-01-01

AUTHORS

VLADIMIR OSIPOV , MARINA BAIDAKOVA , KAZUYUKI TAKAI , TOSHIAKI ENOKI , ALEXANDER VUL

ABSTRACT

Magnetic susceptibility study allows to make certain conclusions about the origin and location of itinerant and localized spins in carbon-based nanomaterials as well as their interaction between themselves. Nanodiamonds (ND) with the mean size about 4-5 nm is an interesting object for studying electronic and magnetic properties of diamond surface throughout its high specific area. Chemically modified ND particle is a very promising new unique material for applications in molecular nano-electronics. Results of recent magnetic studies of pristine and hydrogen-terminated ND samples, obtained by detonation technique, are reported and discussed. In addition to characteristic structural defects, originating from dangling C-C bonds of sp3 sites and located mainly in the interior of the nanocrystals, the hydrogen-terminated ND crystals show a high concentration of excess stable free radicals (up to 1021 spin/g), which are due to structural defects (dangling C-C bonds) induced on the surface of diamond nanocrystals by hydrothermal treatment. Strong antiferromagnetic coupling is found between the spins localized on the surface. More... »

PAGES

447-456

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/1-4020-4367-8_36

DOI

http://dx.doi.org/10.1007/1-4020-4367-8_36

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011279768


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423485.c", 
          "name": [
            "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan", 
            "Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "OSIPOV", 
        "givenName": "VLADIMIR", 
        "id": "sg:person.011737110415.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011737110415.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan", 
          "id": "http://www.grid.ac/institutes/grid.32197.3e", 
          "name": [
            "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "BAIDAKOVA", 
        "givenName": "MARINA", 
        "id": "sg:person.015444514517.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015444514517.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan", 
          "id": "http://www.grid.ac/institutes/grid.32197.3e", 
          "name": [
            "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "TAKAI", 
        "givenName": "KAZUYUKI", 
        "id": "sg:person.016341404751.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016341404751.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan", 
          "id": "http://www.grid.ac/institutes/grid.32197.3e", 
          "name": [
            "Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "ENOKI", 
        "givenName": "TOSHIAKI", 
        "id": "sg:person.011542125231.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011542125231.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423485.c", 
          "name": [
            "Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "VUL", 
        "givenName": "ALEXANDER", 
        "id": "sg:person.014132507145.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014132507145.02"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2006-01-01", 
    "datePublishedReg": "2006-01-01", 
    "description": "Magnetic susceptibility study allows to make certain conclusions about the origin and location of itinerant and localized spins in carbon-based nanomaterials as well as their interaction between themselves. Nanodiamonds (ND) with the mean size about 4-5 nm is an interesting object for studying electronic and magnetic properties of diamond surface throughout its high specific area. Chemically modified ND particle is a very promising new unique material for applications in molecular nano-electronics. Results of recent magnetic studies of pristine and hydrogen-terminated ND samples, obtained by detonation technique, are reported and discussed. In addition to characteristic structural defects, originating from dangling C-C bonds of sp3 sites and located mainly in the interior of the nanocrystals, the hydrogen-terminated ND crystals show a high concentration of excess stable free radicals (up to 1021 spin/g), which are due to structural defects (dangling C-C bonds) induced on the surface of diamond nanocrystals by hydrothermal treatment. Strong antiferromagnetic coupling is found between the spins localized on the surface.", 
    "editor": [
      {
        "familyName": "Gusev", 
        "givenName": "Evgeni", 
        "type": "Person"
      }
    ], 
    "genre": "chapter", 
    "id": "sg:pub.10.1007/1-4020-4367-8_36", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": {
      "isbn": [
        "978-1-4020-4365-9", 
        "978-1-4020-4367-3"
      ], 
      "name": "Defects in High-k Gate Dielectric Stacks", 
      "type": "Book"
    }, 
    "keywords": [
      "carbon-based nanomaterials", 
      "high specific area", 
      "strong antiferromagnetic coupling", 
      "characteristic structural defects", 
      "magnetic susceptibility studies", 
      "stable free radicals", 
      "recent magnetic studies", 
      "detonation technique", 
      "hydrothermal treatment", 
      "ND particles", 
      "magnetic studies", 
      "antiferromagnetic coupling", 
      "structural defects", 
      "diamond surface", 
      "unique material", 
      "Nd crystals", 
      "magnetic properties", 
      "susceptibility studies", 
      "nanodiamonds", 
      "nanocrystals", 
      "pristine", 
      "free radicals", 
      "sp3 sites", 
      "surface", 
      "mean size", 
      "diamond nanocrystals", 
      "ND samples", 
      "nanomaterials", 
      "localized spins", 
      "bonds", 
      "radicals", 
      "high concentrations", 
      "crystals", 
      "particles", 
      "properties", 
      "materials", 
      "specific areas", 
      "spin", 
      "magnetic", 
      "concentration", 
      "interaction", 
      "coupling", 
      "samples", 
      "applications", 
      "size", 
      "addition", 
      "technique", 
      "sites", 
      "interior", 
      "study", 
      "interesting objects", 
      "certain conclusions", 
      "defects", 
      "results", 
      "area", 
      "origin", 
      "treatment", 
      "location", 
      "conclusion", 
      "objects", 
      "promising new unique material", 
      "new unique material", 
      "hydrogen-terminated ND samples", 
      "hydrogen-terminated ND crystals", 
      "excess stable free radicals", 
      "HYDROGENTERMINATED NANODIAMONDS"
    ], 
    "name": "MAGNETIC DEFECTS IN PRISTINE AND HYDROGENTERMINATED NANODIAMONDS", 
    "pagination": "447-456", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1011279768"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/1-4020-4367-8_36"
        ]
      }
    ], 
    "publisher": {
      "name": "Springer Nature", 
      "type": "Organisation"
    }, 
    "sameAs": [
      "https://doi.org/10.1007/1-4020-4367-8_36", 
      "https://app.dimensions.ai/details/publication/pub.1011279768"
    ], 
    "sdDataset": "chapters", 
    "sdDatePublished": "2022-01-01T19:09", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/chapter/chapter_16.jsonl", 
    "type": "Chapter", 
    "url": "https://doi.org/10.1007/1-4020-4367-8_36"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/1-4020-4367-8_36'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/1-4020-4367-8_36'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/1-4020-4367-8_36'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/1-4020-4367-8_36'


 

This table displays all metadata directly associated to this object as RDF triples.

158 TRIPLES      23 PREDICATES      91 URIs      84 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/1-4020-4367-8_36 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N9c397882110d4702aa29e781f03dbfcf
4 schema:datePublished 2006-01-01
5 schema:datePublishedReg 2006-01-01
6 schema:description Magnetic susceptibility study allows to make certain conclusions about the origin and location of itinerant and localized spins in carbon-based nanomaterials as well as their interaction between themselves. Nanodiamonds (ND) with the mean size about 4-5 nm is an interesting object for studying electronic and magnetic properties of diamond surface throughout its high specific area. Chemically modified ND particle is a very promising new unique material for applications in molecular nano-electronics. Results of recent magnetic studies of pristine and hydrogen-terminated ND samples, obtained by detonation technique, are reported and discussed. In addition to characteristic structural defects, originating from dangling C-C bonds of sp3 sites and located mainly in the interior of the nanocrystals, the hydrogen-terminated ND crystals show a high concentration of excess stable free radicals (up to 1021 spin/g), which are due to structural defects (dangling C-C bonds) induced on the surface of diamond nanocrystals by hydrothermal treatment. Strong antiferromagnetic coupling is found between the spins localized on the surface.
7 schema:editor N3ef94968a5fd426d87358892a7a844a4
8 schema:genre chapter
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf Nf0f3d2f790f94a8cad6722a708396848
12 schema:keywords HYDROGENTERMINATED NANODIAMONDS
13 ND particles
14 ND samples
15 Nd crystals
16 addition
17 antiferromagnetic coupling
18 applications
19 area
20 bonds
21 carbon-based nanomaterials
22 certain conclusions
23 characteristic structural defects
24 concentration
25 conclusion
26 coupling
27 crystals
28 defects
29 detonation technique
30 diamond nanocrystals
31 diamond surface
32 excess stable free radicals
33 free radicals
34 high concentrations
35 high specific area
36 hydrogen-terminated ND crystals
37 hydrogen-terminated ND samples
38 hydrothermal treatment
39 interaction
40 interesting objects
41 interior
42 localized spins
43 location
44 magnetic
45 magnetic properties
46 magnetic studies
47 magnetic susceptibility studies
48 materials
49 mean size
50 nanocrystals
51 nanodiamonds
52 nanomaterials
53 new unique material
54 objects
55 origin
56 particles
57 pristine
58 promising new unique material
59 properties
60 radicals
61 recent magnetic studies
62 results
63 samples
64 sites
65 size
66 sp3 sites
67 specific areas
68 spin
69 stable free radicals
70 strong antiferromagnetic coupling
71 structural defects
72 study
73 surface
74 susceptibility studies
75 technique
76 treatment
77 unique material
78 schema:name MAGNETIC DEFECTS IN PRISTINE AND HYDROGENTERMINATED NANODIAMONDS
79 schema:pagination 447-456
80 schema:productId Nccb3db4facdd41ff8d5c7808bedc515f
81 Nd931272dcb1243b6be26e5b3d870ddbc
82 schema:publisher N20460e98ea604858ae7726cfe11f7d6d
83 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011279768
84 https://doi.org/10.1007/1-4020-4367-8_36
85 schema:sdDatePublished 2022-01-01T19:09
86 schema:sdLicense https://scigraph.springernature.com/explorer/license/
87 schema:sdPublisher N585fef0c342e4e9a9fd2b0772ed8be27
88 schema:url https://doi.org/10.1007/1-4020-4367-8_36
89 sgo:license sg:explorer/license/
90 sgo:sdDataset chapters
91 rdf:type schema:Chapter
92 N01b04af2465e4455b461330057dfccbe rdf:first sg:person.016341404751.21
93 rdf:rest N5f08a5a02b974e61a4bfca2e40c3c098
94 N20460e98ea604858ae7726cfe11f7d6d schema:name Springer Nature
95 rdf:type schema:Organisation
96 N3ef94968a5fd426d87358892a7a844a4 rdf:first N7e067d5b265342d5bbf12312d0f09957
97 rdf:rest rdf:nil
98 N585fef0c342e4e9a9fd2b0772ed8be27 schema:name Springer Nature - SN SciGraph project
99 rdf:type schema:Organization
100 N5f08a5a02b974e61a4bfca2e40c3c098 rdf:first sg:person.011542125231.40
101 rdf:rest Ncac5be6f4f4744e9aed445a3e23a3478
102 N7e067d5b265342d5bbf12312d0f09957 schema:familyName Gusev
103 schema:givenName Evgeni
104 rdf:type schema:Person
105 N9c397882110d4702aa29e781f03dbfcf rdf:first sg:person.011737110415.43
106 rdf:rest Ne9183c4d43c14ad499f973aa60163f2a
107 Ncac5be6f4f4744e9aed445a3e23a3478 rdf:first sg:person.014132507145.02
108 rdf:rest rdf:nil
109 Nccb3db4facdd41ff8d5c7808bedc515f schema:name doi
110 schema:value 10.1007/1-4020-4367-8_36
111 rdf:type schema:PropertyValue
112 Nd931272dcb1243b6be26e5b3d870ddbc schema:name dimensions_id
113 schema:value pub.1011279768
114 rdf:type schema:PropertyValue
115 Ne9183c4d43c14ad499f973aa60163f2a rdf:first sg:person.015444514517.48
116 rdf:rest N01b04af2465e4455b461330057dfccbe
117 Nf0f3d2f790f94a8cad6722a708396848 schema:isbn 978-1-4020-4365-9
118 978-1-4020-4367-3
119 schema:name Defects in High-k Gate Dielectric Stacks
120 rdf:type schema:Book
121 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
122 schema:name Chemical Sciences
123 rdf:type schema:DefinedTerm
124 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
125 schema:name Physical Chemistry (incl. Structural)
126 rdf:type schema:DefinedTerm
127 sg:person.011542125231.40 schema:affiliation grid-institutes:grid.32197.3e
128 schema:familyName ENOKI
129 schema:givenName TOSHIAKI
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011542125231.40
131 rdf:type schema:Person
132 sg:person.011737110415.43 schema:affiliation grid-institutes:grid.423485.c
133 schema:familyName OSIPOV
134 schema:givenName VLADIMIR
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011737110415.43
136 rdf:type schema:Person
137 sg:person.014132507145.02 schema:affiliation grid-institutes:grid.423485.c
138 schema:familyName VUL
139 schema:givenName ALEXANDER
140 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014132507145.02
141 rdf:type schema:Person
142 sg:person.015444514517.48 schema:affiliation grid-institutes:grid.32197.3e
143 schema:familyName BAIDAKOVA
144 schema:givenName MARINA
145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015444514517.48
146 rdf:type schema:Person
147 sg:person.016341404751.21 schema:affiliation grid-institutes:grid.32197.3e
148 schema:familyName TAKAI
149 schema:givenName KAZUYUKI
150 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016341404751.21
151 rdf:type schema:Person
152 grid-institutes:grid.32197.3e schema:alternateName Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan
153 schema:name Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan
154 rdf:type schema:Organization
155 grid-institutes:grid.423485.c schema:alternateName Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia
156 schema:name Department of Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152-8551, Tokyo, Japan
157 Ioffe Physico-Technical Institute, 26 Polytechnicheskaya, 194021, St.Petersburg, Russia
158 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...