Mechanism of Cubic Boron Nitride Formation and Phase Equilibria in the Mg—BN and AlN—BN Systems View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2005

AUTHORS

Vladimir Turkevich , Olga Kulik , Pavel Itsenko , A. Andreev , Takashi Taniguchi

ABSTRACT

The mechanism of cubic boron nitride formation in the Mg—BN and AlN—BN systems has been experimentally studied at high pressures and temperatures. In the Mg—BN system, the cBN synthesis proceeds from the liquid phase after melting of the Mg3B2N4 intermediate compound, which was formed previously. The hBN-to-cBN transformation in the AlN—BN system proceeds without a liquid phase. The hexagonal BN dissolves in aluminum nitride solid solution and supersaturates it with respect to cBN. Then cBN precipitates from the supersaturated solution of BN in AlN. A limiting stage of the transformation is the diffusion of boron and nitrogen atoms in wurtzitic aluminum nitride. Activation energy of the transformation is 170±40 kJ/mol. More... »

PAGES

309-318

References to SciGraph publications

Book

TITLE

Innovative Superhard Materials and Sustainable Coatings for Advanced Manufacturing

ISBN

1-4020-3469-5

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/1-4020-3471-7_23

DOI

http://dx.doi.org/10.1007/1-4020-3471-7_23

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016719995


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