Coupled Chemical and Faceting Surface Phase Transitions View Full Text


Ontology type: schema:Chapter     


Chapter Info

DATE

2002

AUTHORS

Paul Wynblatt

ABSTRACT

This paper has summarized results relating to chemical surface phase transitions and roughening faceting transitions which have been observed in Pb-Bi-Ni alloys. The Bi and Ni solutes present in these alloys co-segregate to the surface, and their surface concentrations undergo an abrupt increase on cooling below some transition temperature. This transition temperature depends on the orientation of the surface; it is highest on surfaces of {111} orientation, and is progressively lower on the {227}, {110}, and {100} surfaces, respectively. The temperature dependence of the surface energies of the segregated surfaces is small in the high temperature weakly segregated state, but quite large in the low temperature strongly segregated state. As a consequence, once the transition has occurred at some particular surface orientation, a cusp forms in the γ-plot at that orientation, if one is not already present there. This process leads to the formation of new facets in the alloy which are not seen on the equilibrium form of pure Pb in the same temperature range. More... »

PAGES

231-238

Book

TITLE

Dynamics of Crystal Surfaces and Interfaces

ISBN

0-306-45619-2

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/0-306-47071-3_18

DOI

http://dx.doi.org/10.1007/0-306-47071-3_18

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010945815


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