Reaction of diazonium compound carbene polymerization View Homepage


Ontology type: schema:MonetaryGrant     


Grant Info

YEARS

2010-2013

FUNDING AMOUNT

350000 CNY

ABSTRACT

Diazo compound carbene polymerization of the monomers in recent years developed a new type of reaction, which is the product of the carbon chain of carbon atoms are connected to each polar group carbon chain polymer, and stereochemical control can break conventional olefin polymerization inherent limitations in these areas for the development of unique structure, advanced performance carbon chain polymer provides a new approach in the field of science and high technology has important theoretical value and broad application prospects, is expected to become a polymer the new branch of chemistry. Our polymer chemistry workers reported the first international reaction, Japanese, American and European counterparts have issued some encouraging findings, but the theory is still very preliminary study of the reaction, the present work has focused on specific the level of response, the lack of universal depth, leaving much room for development. The project intends to improve the yield of the chemical reaction of the starting point, in the reaction system screening, optimization of reaction conditions, systematic study undertaken kinetics and mechanism of reactions, from both theoretical and experimental aspects of carbene polymerization the universality of the law have a more in-depth understanding and achieved a number of breakthroughs, prompted the reaction better and wider application areas, so Chinese research in the field of polymer chemistry can be among the international forefront. More... »

URL

http://npd.nsfc.gov.cn/projectDetail.action?pid=21074097

Related SciGraph Publications

  • 2016-09. Metal-Diazo Radicals of α-Carbonyl Diazomethanes in SCIENTIFIC REPORTS
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